56851-34-4Relevant academic research and scientific papers
Silver-catalyzed benzylation and allylation reactions of tertiary and secondary alkyl halides with grignard reagents
Someya, Hidenori,Ohmiya, Hirohisa,Yorimitsu, Hideki,Oshima, Koichiro
scheme or table, p. 969 - 971 (2009/04/10)
Treatment of alkyl halides, including tertiary alkyl bromides, with benzylic or allylic Grignard reagent in the presence of a catalytic amount of silver nitrate in ether yielded the corresponding cross-coupling products in high yields. The coupling reactions of tertiary alkyl halides provide efficient access to quaternary carbon centers.
