56892-38-7

Upstream product

• 617-86-7 triethylsilane 
• 34713-70-7 2-Phenylpropanal 
• 18296-01-0 triethylsilyl formate 
• 1123-85-9 (RS)-2-phenyl-1-propanol 
• 18406-24-1 1-(triethylsilyloxy)-4-methoxybenzene 
• 994-30-9 triethylsilyl chloride 

Relevant academic research and scientific papers

Iron-Catalyzed Silylation of Alcohols by Transfer Hydrosilylation with Silyl Formates

An iron catalyst is shown for the first time to promote transfer hydrosilylation with silyl formates and is utilized for the silylation of alcohols. Attractive features of this protocol include the use of an earth-abundant transition-metal catalyst, mild reaction conditions, and the release of gases as the only byproducts (H 2 and CO 2).

Use of Silylated Formiates as Hydrosilane Equivalents

The present invention relates to a method for preparing organic compounds of formula (I) by reaction between a silylated formiate of formula (II) and an organic compound in the presence of a catalyst and optionally of an additive. The invention also relates to use of the method for preparing organic compounds of formula (I) for the preparation of reagents for fine chemistry and for heavy chemistry, as well as in the production of vitamins, pharmaceutical products, adhesives, acrylic fibres, synthetic leathers, and pesticides.

Silylation of O-H bonds by catalytic dehydrogenative and decarboxylative coupling of alcohols with silyl formates

The silylation of O-H bonds is a useful methodology in organic synthesis and materials science. While this transformation is commonly achieved by reacting alcohols with reactive chlorosilanes or hydrosilanes, we show herein for the first time that silylformates HCO2SiR3 are efficient silylating agents for alcohols, in the presence of a ruthenium molecular catalyst.

Ruthenium catalyzed selective hydrosilylation of aldehydes

A chemoselective hydrosilylation method for aldehydes is developed using a ruthenium catalyst [(Ru(p-cymene)Cl2)2] and triethylsilane; a mono hydride bridged dinuclear complex [{(η6-p- cymene)RuCl}2(μ-H-μ-Cl)] a

Rhodium-catalyzed, efficient deutero- and tritiosilylation of carbonyl compounds from hydrosilanes and deuterium or tritium

A cationic rhodium compound which is an active catalyst for both the hydrogen isotope exchange in hydrosilanes and the hydrosilylation of carbonyl compounds permits, in a one-flask, two-step procedure, efficient deutero- and tritiosilylations using SiEt3H under D2 (0.5 bar) or T2, at low catalyst loadings (0.1-0.5 mol %).

A convenient and efficient rhenium-Catalyzed hydrosilylation of ketones and aldehydes

The easily available rhenium(I) complex [Re(CH3CN) 3Br2(NO)] catalyzes the homogeneous hydrosilylation of a great variety of organic carbonyl compounds (ketones and aldehydes). The reaction is quite sensitive to the solven