56892-38-7

Basic information

• Product Name: 1-phenyl-1-((triethylsilyloxy)methyl)ethane
• Synonyms: 1-phenyl-1-((triethylsilyloxy)methyl)ethane
• CAS NO: 56892-38-7
• Molecular Weight: 250.456
• Mol File: 56892-38-7.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 1-phenyl-1-((triethylsilyloxy)methyl)ethane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenyl-1-((triethylsilyloxy)methyl)ethane(56892-38-7)
• EPA Substance Registry System: 1-phenyl-1-((triethylsilyloxy)methyl)ethane(56892-38-7)

Safety Data

• Hazardous Substances Data: 56892-38-7(Hazardous Substances Data)

Upstream product

• 617-86-7 triethylsilane 
• 34713-70-7 2-Phenylpropanal 
• 18296-01-0 triethylsilyl formate 
• 1123-85-9 (RS)-2-phenyl-1-propanol 
• 18406-24-1 1-(triethylsilyloxy)-4-methoxybenzene 
• 994-30-9 triethylsilyl chloride 

Relevant articles and documents

Iron-Catalyzed Silylation of Alcohols by Transfer Hydrosilylation with Silyl Formates

An iron catalyst is shown for the first time to promote transfer hydrosilylation with silyl formates and is utilized for the silylation of alcohols. Attractive features of this protocol include the use of an earth-abundant transition-metal catalyst, mild reaction conditions, and the release of gases as the only byproducts (H 2 and CO 2).

Silylation of O-H bonds by catalytic dehydrogenative and decarboxylative coupling of alcohols with silyl formates

The silylation of O-H bonds is a useful methodology in organic synthesis and materials science. While this transformation is commonly achieved by reacting alcohols with reactive chlorosilanes or hydrosilanes, we show herein for the first time that silylformates HCO2SiR3 are efficient silylating agents for alcohols, in the presence of a ruthenium molecular catalyst.

Rhodium-catalyzed, efficient deutero- and tritiosilylation of carbonyl compounds from hydrosilanes and deuterium or tritium

A cationic rhodium compound which is an active catalyst for both the hydrogen isotope exchange in hydrosilanes and the hydrosilylation of carbonyl compounds permits, in a one-flask, two-step procedure, efficient deutero- and tritiosilylations using SiEt3H under D2 (0.5 bar) or T2, at low catalyst loadings (0.1-0.5 mol %).