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(3S,4S)-3,4-dihydrophenanthrene-3,4-diol is a chiral organic compound belonging to the phenanthrene family. It is characterized by its unique structure, where two hydroxyl groups are attached to the 3 and 4 positions of the dihydrophenanthrene core. The compound exhibits a specific stereochemistry, with the 3 and 4 carbon atoms having the S configuration. This chirality plays a crucial role in its potential applications, as it can influence the compound's reactivity and biological activity. (3S,4S)-3,4-dihydrophenanthrene-3,4-diol is of interest in various fields, including pharmaceuticals and materials science, due to its unique properties and potential for further functionalization.

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  • 569-20-0 Structure
  • Basic information

    1. Product Name: (3S,4S)-3,4-dihydrophenanthrene-3,4-diol
    2. Synonyms: 3,4-Phenanthrenediol, 3,4-dihydro-, (3S-trans)-
    3. CAS NO:569-20-0
    4. Molecular Formula: C14H12O2
    5. Molecular Weight: 212.2439
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 569-20-0.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 435°C at 760 mmHg
    3. Flash Point: 217.5°C
    4. Appearance: N/A
    5. Density: 1.346g/cm3
    6. Vapor Pressure: 2.46E-08mmHg at 25°C
    7. Refractive Index: 1.741
    8. Storage Temp.: N/A
    9. Solubility: N/A
    10. CAS DataBase Reference: (3S,4S)-3,4-dihydrophenanthrene-3,4-diol(CAS DataBase Reference)
    11. NIST Chemistry Reference: (3S,4S)-3,4-dihydrophenanthrene-3,4-diol(569-20-0)
    12. EPA Substance Registry System: (3S,4S)-3,4-dihydrophenanthrene-3,4-diol(569-20-0)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 569-20-0(Hazardous Substances Data)

569-20-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 569-20-0 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 5,6 and 9 respectively; the second part has 2 digits, 2 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 569-20:
(5*5)+(4*6)+(3*9)+(2*2)+(1*0)=80
80 % 10 = 0
So 569-20-0 is a valid CAS Registry Number.

569-20-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name phenanthrene trans-3,4-dihydrodiol

1.2 Other means of identification

Product number -
Other names trans-3,4-Dihydroxy-3,4-dihydrophenathren

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:569-20-0 SDS

569-20-0Downstream Products

569-20-0Relevant articles and documents

Synthesis of the o-Quinones and Dihydro Diols of Polycyclic Aromatic Hydrocarbons from the Corresponding Phenols

Sukumaran, K.B.,Harvey, Ronald G.

, p. 4407 - 4413 (2007/10/02)

Terminal-ring trans-dihydro diol metabolites have been implicated as the ultimate carcinogenic forms of polycyclic aromatic hydrocarbons.Synthesis of these dihydro diols from the related polycyclic phenols in two steps via oxidation to the corresponding o-quinones with either Fremy's salt or phenylseleninic anhydride followed by stereospecific reduction with lithium aluminum hydride is described.The non-K-region quinones and trans-dihydro diols of naphthalene, anthracene, phenanthrene, benzanthracene, benzopyrene, and 7,12-dimethylbenzanthracene are synthesized via this approach.Although poor yields (1-4percent) were previously reported for the reduction of non-K-region quinones, an improved experimental procedure has been developed which affords the trans-dihydro diols free of the isomeric cis-dihydro diols in generally good yields.Major byproducts are the corresponding hydroquinones, previously undetected, and the related tetrahydro diols.The latter are the major products of reduction of the poorly soluble quinones of benzopyrene and benzanthracene and are shown to arise through further reduction of the dihydro diols.Since the tetrahydro diols are convertible to dihydro diols and the hydroquinones are reoxidizable to quinones, good overall conversions of quinones to dihydro diols are attainable. trans-3,4-Dihydroxy-3,4-dihydro-7,12-dimethylbenzanthracene synthesized in these studies is the most potent tumorigenic hydrocarbon metabolite tested to date.

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