56937-47-4Relevant academic research and scientific papers
Hydrosilylation of epoxides catalyzed by a cationic η1- silane iridium(iii) complex
Park, Sehoon,Brookhart, Maurice
, p. 3643 - 3645 (2011)
Cationic silane complex 2, catalyzes the hydrosilylation of epoxides and cyclic ethers to give the silyl-protected alcohols, regioselectively. A mechanistic study shows that the epoxide undergoes isomerization to the ketone, followed by hydrosilylation.
Carbonyl and olefin hydrosilylation mediated by an air-stable phosphorus(iii) dication under mild conditions
Andrews, Ryan J.,Chitnis, Saurabh S.,Stephan, Douglas W.
supporting information, p. 5599 - 5602 (2019/05/21)
The readily-accessible, air-stable Lewis acid [(terpy)PPh][B(C6F5)4]21 is shown to mediate the hydrosilylation of aldehydes, ketones, and olefins. The utility and mechanism of these hydrosilylations are considered.
A Versatile Iridium(III) Metallacycle Catalyst for the Effective Hydrosilylation of Carbonyl and Carboxylic Acid Derivatives
Corre, Yann,Rysak, Vincent,Trivelli, Xavier,Agbossou-Niedercorn, Francine,Michon, Christophe
supporting information, p. 4820 - 4826 (2017/09/07)
A versatile iridium(III) metallacycle catalysed rapidly and selectively the reduction of a large array of challenging esters and carboxylic acids as well as various ketones and aldehydes. The reactions proceeded in high yields at room temperature by hydrosilylation followed by desilylation. Although the reactions of various aldehydes and ketones resulted exclusively in alcohols, the hydrosilylation of esters led to alcohols or ethers, depending on the type of substrate. Regarding the carboxylic acids, again the nature of the reagent controlled the outcome of the hydrosilylation reaction, either alcohols or aldehydes being formed.
