56946-66-8Relevant academic research and scientific papers
Garcinol derivative and application thereof
-
Paragraph 0013, (2018/07/30)
The invention discloses a garcinol derivative or a pharmaceutically acceptable salt (I) thereof, which comprises a stereoisomer or a tautomer. The invention relates to a preparation method of the compound and a use of the compound in medicine for preventi
Biomimetic-Inspired Syntheses of Myrtucommuacetalone and Myrtucommulone J
Liu, Hongxin,Huo, Luqiong,Yang, Bao,Yuan, Yunfei,Zhang, Weimin,Xu, Zhifang,Qiu, Shengxiang,Tan, Haibo
supporting information, p. 4786 - 4789 (2017/09/23)
Driven by bioinspiration and appreciation of their structures, the first biomimetic total syntheses with structural revision of the acylphloroglucinols myrtucommulone J and myrtucommuacetalone, two biologically meaningful natural products, were achieved through a biosynthetic hemiacetalization/dehydration/[3 + 3]-type cycloaddition domino sequence with high step efficiency. These syntheses result in a corrected structure for myrtucommulone J.
Development of a strategy for the asymmetric synthesis of polycyclic polyprenylated acylphloroglucinols via N-amino cyclic carbamate hydrazones: Application to the total synthesis of (+)-clusianone
Garnsey, Michelle R.,Lim, Daniel,Yost, Julianne M.,Coltart, Don M.
scheme or table, p. 5234 - 5237 (2011/02/23)
A broadly applicable asymmetric synthetic strategy utilizing N-amino cyclic carbamate alkylation that provides access to the various stereochemical permutations of a common structural motif found in many polycyclic polyprenylated acylphloroglucinols is de
An efficient method for construction of the angularly fused 6,3,5-tricyclic skeleton of mycorrhizin A and its analogues
Yu, Binxun,Jiang, Tuo,Quan, Weiguo,Li, Junpeng,Pan, Xinfu,She, Xuegong
supporting information; experimental part, p. 629 - 632 (2009/07/25)
(Chemical Equation Presented) The angularly fused 6,3,5-tricyclic system is readily generated via a cascade cyclization under acid promotion. The reaction proceeds at room temperature with high stereochemical fidelity from the electrophilic center of the
