56950-08-4Relevant academic research and scientific papers
Synthesis of alkynyltellurides mediated by K3PO4 and DMSO
Do Sacramento, Manoela,Menezes, Larissa,Goldani, Bruna,Perin, Gelson,Silva, Marcio S.,Barcellos, Thiago,Alves, Diego
supporting information, p. 11091 - 11098 (2019/07/31)
In the present work, a simple method for the synthesis of alkynyltellurides is described by the reactions of terminal alkynes with diorganyl ditellurides in the presence of a catalytic amount of K3PO4. In both substrates, it was possible to vary the aryl and alkyl groups, obtaining the products of interest in short reaction times and in yields ranging from 30 to 93%. This methodology, different from those already reported in the literature, has the advantage of using a catalytic amount of a weak base and no use of metallic catalysts.
Magnetite (Fe3O4) nanoparticles: An efficient and recoverable catalyst for the synthesis of alkynyl chalcogenides (selenides and tellurides) from terminal acetylenes and diorganyl dichalcogenides
Godoi, Marcelo,Liz, Daiane G.,Ricardo, Eduardo W.,Rocha, Manuela S.T.,Azeredo, Juliano B.,Braga, Antonio L.
, p. 3349 - 3354 (2014/05/06)
We present herein a new and efficient methodology for the synthesis of alkynyl chalcogenides from terminal acetylenes and diorganyl dichalcogenides, catalyzed by Fe3O4 nanoparticles. This new approach provided the desired products in good to excellent yields. Moreover, the catalyst was easily recoverable using an external magnet and reused for further experiments without loss of catalytic activity.
A General and highly efficient protocol for the synthesis of chalcogenoacetylenes by copper(I)-terpyridine catalyst
Movassagh, Barahman,Yousefi, Ali,Momeni, Badri Zaman,Heydari, Sepideh
, p. 1385 - 1390 (2014/06/23)
A highly efficient copper-catalyzed Csp-X (X = S, Se, Te) bond-forming reaction of terminal alkynes and diorganyl dichalcogenides has been developed. This transformation was realized through the use of copper(I) iodide as a catalyst, 4′-(4-meth
Cesium hydroxide-catalyzed reaction of terminal alkynes with diarylditellurides to synthesize alkynyl tellurides
Zou, Kang Bing,Qiu, Ren Hua,Fang, Da Wei,Liu, Xin You,Xu, Xin Hua
, p. 2237 - 2242 (2008/09/21)
In the presence of a catalytic amount of cesium hydroxide under an air atmosphere, the reaction of diarylditellurides (1.0 mmol) with terminal alkynes (2.2 mmol) at room temperature exclusively give alkynyl tellurides in good yields. Copyright Taylor & Fr
Hypervalent iodine in synthesis XXVI: A convenient synthesis of acetylenic tellurides
Zhang, Jun-Lian,Chen, Zhen-Chu
, p. 3881 - 3885 (2007/10/03)
Acetylenic tellurides have been prepared by the reaction of sodium arenetellurolates with alkynylphenyliodonium tosylates in DMF.
