56970-75-3Relevant academic research and scientific papers
Highly regioselective intramolecular hydroxymethylation of α,β-unsaturated carboxylic acids
Linker, Torsten,Maurer, Michael,Rebien, Frank
, p. 8363 - 8366 (2007/10/03)
A convenient synthesis of hydroxy esters 7 and lactones 8 by starting from easily available α,β-unsaturated carbocylic acids 4 is described. The key step of this transformation is a hitherto unknown radical cyclization of silyl esters, which exhibits a high degree of regioselectivity through steric and orbital control.
HYDROFORMYLATION OF OLEFINS WITH PARAFORMALDEHYDE CATALYZED BY RHODIUM COMPLEXES
Okano, Tamon,Kobayashi, Teruyuki,Konishi, Hisatoshi,Kiji, Jitsuo
, p. 4967 - 4968 (2007/10/02)
The addition of formaldehyde to olefins is efficiently catalyzed by RhH2(O2COH)2 and gives the corresponding aldehydes in neutral solution.
