57056-87-8Relevant academic research and scientific papers
1,3-disubstituted indoline derivative and preparation method thereof
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Paragraph 0072; 0073; 0074, (2020/02/27)
The invention relates to a 1,3-disubstituted indoline derivative and a preparation method thereof, and belongs to the field of organic compound synthesis. The preparation method comprises following steps: step one, according to a mole ratio of (1-3): (2-1
Radical Hydrodeiodination of Aryl, Alkenyl, Alkynyl, and Alkyl Iodides with an Alcoholate as Organic Chain Reductant through Electron Catalysis
Dewanji, Abhishek,Mück-Lichtenfeld, Christian,Studer, Armido
supporting information, p. 6749 - 6752 (2016/06/09)
A simple and efficient method for radical hydrodeiodination is reported. The novel approach uses electron catalysis. In situ generated Na-alcoholates are introduced as radical chain reducing reagents and reactions work with O2as cheap initiator. Hydrodeiodination works on aryl, alkenyl, alkynyl iodides and a tert-alkyl iodide also gets reduced applying the method. Albeit less general, the method is also applicable to the reduction of aryl bromides. The novel reagent is successfully used to conduct typical reductive radical cyclization reactions and mechanistic studies are reported.
