57060-75-0Relevant academic research and scientific papers
Lewis acid catalyzed stereoselective carbosilylation. Intramolecular trans-vinylsilylation and trans-arylsilylation of unactivated alkynes
Asao,Shimada,Shimada,Yamamoto
, p. 10899 - 10902 (2001)
Intramolecular trans-vinylsilylation using silicon-tethered alkynylvinylsilanes 3b-c was catalyzed dramatically by Lewis acids such as EtAlCl2 to give the corresponding six-membered silacycles 4b-c in high yields. The reaction proceeded via an
Palladium Catalyzed Reaction of Silacyclobutanes with Acetylenes
Takeyama, Yoshihiro,Nozaki, Kyoko,Matsumoto, Kozo,Oshima, Koichiro,Utimoto, Kiitiro
, p. 1461 - 1466 (2007/10/02)
Whereas the reaction of 1,1-dimethyl-1-silacyclobutane (1a) with dimethyl acetylenedicarboxylate in the presence of Pd catalyst provides dimethyl 1,1-dimethyl-1-sila-2-cyclohexene-2,3-dicarboxylate almost exclusively, the reaction of 1a with phenylacetyle
