571185-82-5Relevant academic research and scientific papers
New oxidative tools for the functionalization of the cephalostatin North 1 hemisphere
Lee, Jong Seok,Fuchs, Philip L.
, p. 2247 - 2250 (2003)
(Matrix presented) Dimethyldioxirane (DMDO) C-H oxidation of ketone 17 to hemiketal 18 (82%), bis-dehydration to vinyl ether 21 (77%), and DMDO again provides C-23 axial alcohol 23 (99%). Routine processing, including a double-stereoselective Sharpless AD
