571201-35-9

Upstream product

• 824-94-2 p-methoxybenzyl chloride 
• 571201-28-0 (2S,3R,4R,5S)-4-Benzyloxy-5-((R)-1-benzyloxy-ethyl)-2-pent-4-enyloxy-tetrahydro-furan-3-ol 
• 10257-28-0 D-Galactose 
• 1119-51-3 bromopentene 
• 571201-33-7 2,2-Dimethyl-propionic acid (2S,3R,4S,5S)-4-benzyloxy-5-[(R)-1-benzyloxy-2-(toluene-4-sulfonyloxy)-ethyl]-2-pent-4-enyloxy-tetrahydro-furan-3-yl ester 
• 571201-31-5 2,2-Dimethyl-propionic acid (2S,3R,4S,5S)-4-hydroxy-5-{(R)-1-hydroxy-2-[(4-methoxy-phenyl)-diphenyl-methoxy]-ethyl}-2-pent-4-enyloxy-tetrahydro-furan-3-yl ester 
• 571201-30-4 (2S,3R,4R,5S)-2-{(R)-1-Hydroxy-2-[(4-methoxy-phenyl)-diphenyl-methoxy]-ethyl}-5-pent-4-enyloxy-tetrahydro-furan-3,4-diol 
• 571201-32-6 2,2-Dimethyl-propionic acid (2S,3R,4S,5S)-4-benzyloxy-5-((R)-1-benzyloxy-2-hydroxy-ethyl)-2-pent-4-enyloxy-tetrahydro-furan-3-yl ester 
• 172975-15-4 n-pentenyl α-D-galactofuranoside 
• 172975-17-6 pent-4-enyl 2,3,5,6-tetra-O-acetyl-α-D-galactofuranoside 

Relevant academic research and scientific papers

First intramolecular aglycon delivery onto a D-fucofuranosyl entity for the synthesis of α-D-fucofuranose-containing disaccharides

Intramolecular aglycon delivery was performed for the first time starting from n-pentenyl glycofuranoside as a donor. p-Methoxybenzyl-assisted aglycon transfer required very mild reaction conditions and was promoted by N-iodosuccinimide without assistance of any Lewis acid catalyst. As a result, rare α-D-fucofuranose-containing disaccharides were obtained. Moreover, structure elucidation led to the conclusion that an N-succinimidyl residue was still present in the resulting products. Wiley-VCH Verlag GmbH & Co, KGaA, 69451 Weinheim, Germany, 2003.