571202-87-4

Basic information

• Product Name: (3-BROMOPHENOXY)TRIISOPROPYLSILANE 97
• Synonyms: (3-BROMOPHENOXY)TRIISOPROPYLSILANE 97;(3-BROMOPHENOXY)TRIISOPROPYLSILANE;(3-Bromophenoxy)triisopropylsilane 97%
• CAS NO: 571202-87-4
• Molecular Formula: C₁₅H₂₅BrOSi
• Molecular Weight: 329.3479
• Mol File: 571202-87-4.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 313.269°C at 760 mmHg
• Flash Point: 143.26°C
• Appearance: /
• Density: 1.103g/cm³
• Vapor Pressure: 0.001mmHg at 25°C
• Refractive Index: 1.49
• CAS DataBase Reference: (3-BROMOPHENOXY)TRIISOPROPYLSILANE 97(CAS DataBase Reference)
• NIST Chemistry Reference: (3-BROMOPHENOXY)TRIISOPROPYLSILANE 97(571202-87-4)
• EPA Substance Registry System: (3-BROMOPHENOXY)TRIISOPROPYLSILANE 97(571202-87-4)

Safety Data

• Hazardous Substances Data: 571202-87-4(Hazardous Substances Data)

Usage

General Description

(3-Bromophenoxy)triisopropylsilane 97 is a chemical compound that is primarily used as a reagent in organic synthesis. It is a trialkylsilyl halide derivative, and its main function is as a reagent for the preparation of various organic compounds. (3-BROMOPHENOXY)TRIISOPROPYLSILANE 97 is known for its use in the synthesis of various pharmaceutical drugs, agrochemicals, and other biologically active molecules. It is also used in the production of various polymers and materials. Overall, (3-Bromophenoxy)triisopropylsilane 97 is an important reagent in the field of organic chemistry and has a wide range of applications in industrial and academic research.

InChI:InChI=1/C15H25BrOSi/c1-11(2)18(12(3)4,13(5)6)17-15-9-7-8-14(16)10-15/h7-13H,1-6H3

Upstream product

• 13154-24-0 triisopropylsilyl chloride 
• 591-20-8 3-Bromophenol 
• 288-32-4 1H-imidazole 
• 80522-42-5 triisopropylsilyl trifluoromethanesulfonate 

Downstream Products

• 862261-23-2 4-(3-triisopropylsilanyloxy-phenyl)-piperazine-1-carboxylic acid tert-butyl ester 
• 1644060-71-8 methyl 2-methoxy-4-{[3-(triisopropylsilyloxy)phenyl]amino}benzoate 
• 1083248-48-9 3-[(1,1,1-triisopropylsilyl)oxy]phenylboronic acid 
• 1428743-75-2 13-hydroxy-1-(3-hydroxyphenyl)-1-tridecanone 
• 1345027-83-9 C₂₄H₃₅NO₄Si 
• 1072127-13-9 C₂₃H₃₂N₂O₂Si 
• 791131-66-3 5-[hydroxy-(3-triisopropylsilanyloxy-phenyl)-methyl]-4a-methyl-4,4a,5,6,7,8-hexahydro-3H-naphthalen-2-one 
• 540751-83-5 4-[3-(5-amino-2-furan-2-yl-[1,2,4]triazolo[1,5-c]pyrimidin-7-yl)-phenyl]-piperazine-1-carboxylic acid tert-butyl ester 

Relevant articles and documents

CELL-PENETRATING FLUORESCENT DYES WITH SECONDARY ALCOHOL FUNCTIONALITIES

The invention relates to novel cell-penetrating fluorescent dyes with with secondary alcohol functionalities having one of the following general formulae I-III and 4: The invention also relates to the use of these compounds for optical microscopy and imaging techniques.

Total syntheses of murrayamine E, I, and K

We describe efficient synthetic routes to murrayamine A (mukoenine C), O-methylmurrayamine A, mahanine, O-methylmahanine, and murrayamine D and the first total syntheses of murrayamine E, I, and K. Key steps are a palladium-catalyzed construction of the carbazole framework and an annulation of the pyran ring, which is either catalyzed by phenylboronic acid or promoted by a Lewis acid.

Total synthesis of 7- and 8-oxygenated pyrano[3,2-a]carbazole and pyrano[2,3-a]carbazole alkaloids via boronic acid-catalyzed annulation of the pyran ring

The boronic acid-catalyzed annulation of citral opens up a short route to oxygenated cyclized monoterpenoid pyranocarbazole alkaloids. Thus, murrayamine-D is available in only three steps and 55% overall yield from the corresponding carbazole precursor.