57153-67-0Relevant academic research and scientific papers
Behavior of benzoins and hydroxy ketones in acid media: I. Reaction of 1-aryl-2-(2,5-dimethylthiophen-3-yl)-2-hydroxyethanones with thiols in trifluoroacetic acid
Krayushkin,Lichitskii,Mikhalev,Dudinov,Ivanov
, p. 87 - 90 (2005)
Reactions of 1-aryl-2-(2,5-dimethylthiophen-3-yl)-2-hydroxyethanones with thiols in trifluoroacetic acid lead to formation of substituted 1-aryl-2-(2,5-dimethylthiophen-3-yl)-2-sulfanylethanones. 2005 Pleiades Publishing, Inc.
Synthesis and photochromism of some mono and bis (thienyl) substituted oxathiine 2,2-dioxides
Aiken, Stuart,Gabbutt, Christopher D.,Heron, B. Mark,Rice, Craig R.,Zonidis, Dimitrios
, p. 9578 - 9584 (2019/11/20)
1,2-Oxathiine 2,2-dioxides have been obtained from their respective 3,4-dihydro-4-dimethylamino precursors, for the first time, by a mild Cope elimination of the 4-dimethylamino function. The application of the 1,2-oxathiine 2,2-dioxide scaffold in materi
Transition-Metal-Free Intermolecular α-Arylation of Ketones via Enolonium Species
Maksymenko, Shimon,Parida, Keshaba N.,Pathe, Gulab K.,More, Atul A.,Lipisa, Yuriy B.,Szpilman, Alex M.
, p. 6312 - 6315 (2017/12/08)
Herein it is shown, for the first time, that enolonium species are powerful electrophiles capable of reacting with aromatic compounds in an intermolecular manner to afford α-arylated ketones. The reaction is compatible with a variety of functional groups, is of wide scope with respect to aromatic compounds and ketone, and even works for polymerization-prone substrates such as substituted pyrroles, thiophenes, and furans. Only 1.6 to 5 equiv of the commodity aromatic substrates is needed.
