57266-90-7

Upstream product

• 6224-91-5 trimethyl(prop-1-ynyl)silane 
• 108-86-1 bromobenzene 
• 99966-31-1 10-((Z)-1-Trimethylsilanyl-propenyl)-9-oxa-10-bora-bicyclo[3.3.2]decane 
• 5908-41-8 benzoyltrimethylsilane 

Downstream Products

• 103980-87-6 (R)-trimethyl(1-phenylpropyl)silane 
• 103980-90-1 (S)-trimethyl(1-phenylpropyl)silane 

Relevant academic research and scientific papers

Iridium-Catalyzed Enantioselective Hydrogenation of Vinylsilanes

We have screened a diverse array of iridium complexes derived from chiral N,P ligands as catalysts for the asymmetric hydrogenation of vinylsilanes, a transformation for which generally applicable catalysts were lacking. Several catalysts emerged from thi

A synthesis of multisubstituted vinylsilanes via ynolates: Stereoselective formation of β-silyl-β-lactones followed by decarboxylation

(Z)-Selective synthesis of multisubstituted vinylsilanes was achieved by stereoselective protonation or alkylation of β-silyl-β-lactone enolates, prepared by cycloadditions of acylsilanes with ynolates, followed by decarboxylation. The Royal Society of Ch

The efficient stereoselective synthesis of Z-vinylsilanes through the Suzuki-Miyaura coupling of Z-(α-silylvinyl)borinates

Air-stable Z-(α-silylvinyl)borinates (2), easily prepared in a hydroboration-oxidation sequence from I provide a particularly effective route to Z-vinylsilanes (3, 59-97%) through Suzuki-Miyaura coupling.

Z-trimethylsilyl styrenes and 1,3-dienes via the Suzuki reaction

Representative vinyl and aryl bromides are cross-coupled, under basic conditions, to Z-α-trimethylsilylvinylboranes with tetrakis(triphenylphosphine)palladium(O) catalyst to provide the corresponding silylated styrenes and 1,3-dienes (40-60%, >98% Z).