57295-53-1Relevant academic research and scientific papers
Thiocyanation of N,N-Dialkylhydrazonoyl Bromides: An Entry to Sulfur-Containing 1,2,4-Triazole Derivatives
Prieto, Alexis,Uzel, Alexandre,Bouyssi, Didier,Monteiro, Nuno
, p. 4201 - 4204 (2017)
A simple and practical one-pot protocol involving sequential C–H bromination and thiocyanation of readily available aldehyde-derived N,N-dialkylhydrazones has been established for the synthesis of 5-thioxo-1,2,4-triazolium inner salts. Application of the method toward the synthesis of value-added 3-sulfanyl-1,2,4-triazoles through N→S alkyl group transfer has also been demonstrated.
