57336-16-0Relevant academic research and scientific papers
Thermal reactions involving 1-azadienes and allenic esters-(II):1a reactions of 3-(N-aryliminomethyl)chromones with allenic esters-tandem reorganization of [2+2] cycloadducts to novel compounds
Kapur, Ashish,Sharma, Vishal,Kaur, Amandeep,Parashar, Poonam,Kanwal, Priyanka,Gupta, Vivek,Ishar, Mohan Paul S.
, p. 4784 - 4787 (2015)
Thermal reactions of 3-(N-aryliminomethyl)chromones (4a-d) with ethyl 2,3-butadienoate (5a) and ethyl 4-phenyl-2,3-butadienoate (5b), on refluxing in dry benzene, afford novel compounds 6a-e, apparently, derived from tandem reorganization of initially formed [2+2] cycloadducts. However, reaction of 4a,d with ethyl 2,3-pentadienoate (5c, R = CH3) under similar condition follows a different course yielding novel molecules 7a,d and 8a,d. Plausible mechanistic rationale for the formation of new molecules is proffered.
Calcium Chloride/HCl an efficient co-catalytic system for synthesis of 3-(Aryliminomethyl)-Chromones under sonochemical condition
Kulkarni, Pramod S.
, p. 23 - 27 (2016/07/15)
(Formula presented) Calcium Chloride and one drop concentrated HCl has been found to be an efficient catalyst for the synthesis of 3-(Aryliminomethyl)-Chromones (3) from 3-Formylchromones (1) and amines (2) under ultrasound condition. The reaction under ultrasound condition proceeds in high yields at ambient temperature in a short time. A variety of imines have been synthesized by varying substituent on aromatic amines in good yields.
Indium triflate: A new catalyst for (4 + 2)-cycloaddition of chromone Schiff's bases
Gadhwal, Sunil,Sandhu, Jagir S.
, p. 2827 - 2829 (2007/10/03)
Indium triflate was introduced as a new catalyst for (4+2)-cycloaddition of chromone Schiff's bases. 3,4-Dihydro-2H-pyran reacted with a variety of chromone Schiff's bases in the presence of indium and scandium triflates at ambient temperature and pressur
Studies on Chromone Derivatives. A Direct and Efficient One-pot Synthesis of 4-Chromone-linked 3-(N-Acylamino)azetidin-2-ones from Imines and N-Acylalanine
Prajapati, Dipak,Mahajan, Asha R.,Sandhu, Jagir S.
, p. 1821 - 1824 (2007/10/02)
Chlorosulfonylmethylene(dimethyl)ammonium chloride 1 is found to be an efficient cyclodehydrating agent for the one-pot synthesis of various novel chromone-linked azetidin-2-ones 6 via cycloaddition reactions of 3-(arylaminomethyl)chromones 5 with in situ
STUDIES IN CHROMONE DERIVATIVES: CYCLOADDITION REACTIONS OF 4-OXO-4H-1-BENZOPYRAN-3-CARBOXALDEHYDE IMINES WITH BENZONITRILE OXIDE AND NITRILIMINE OF 4-OXO-4H-1-BENZOPYRAN-3-CARBOXALDEHYDE WITH ALKENES
Baruah, Arpan Kumar,Prajapati, Dipak,Sandhu, Jagir Singh
, p. 1241 - 1246 (2007/10/02)
The chromone imines 1 and benzonitrile oxide reacted regiospecifically to yield Δ2-1,2,4 oxadiazolinyl chromones 2 in good yields.Also the preparation of a novel dipole 6 derived from 3-formylchromone and its cycloaddition reactions with a vari
STUDIES ON CHROMONE DERIVATIVES. NOVEL 1,3 DIPOLAR CYCLOADDITIONS OF 4-OXO-1-BENZOPYRAN-3-CARBALDEHYDE IMINES AND IMINE OXIDES
Baruah, Arpan K.,Prajapati, Dipak,Sandhu, Jagir S.
, p. 1995 - 1998 (2007/10/02)
The chromone imines (2) and nitrile imines (4) reacted smoothly to yield the novel 1,2,4-triazolinyl- and triazepinyl-chromones, (6) and (5) respectively.The facile preparation of nitrones of chromones and their selected reactions with a variety of alkenes to obtain isoxazolidinylchromones (12) is also described.
