57356-79-3Relevant articles and documents
A concise, stereocontrolled total synthesis of rippertenol
Snyder, Scott A.,Wespe, Daniel A.,Von Hof, J. Marian
supporting information; experimental part, p. 8850 - 8853 (2011/08/04)
The first total synthesis of the unique terpene rippertenol, a molecule with dense stereochemical complexity arrayed on a compact framework largely devoid of functional groups, is described. Key elements include orchestrated and unique applications of aldol condensations, Diels-Alder chemistry, and a ring expansion to advance a chiral starting material containing a single chiral center into the final target in a concise and diastereocontrolled manner.
Synthesis of optically active cyclohexenol derivatives via enzyme catalyzed ester hydrolysis of 4-acetoxy-3-methyl-2-cyclohexenone
Polla, Magnus,Frejd, Torbjoern
, p. 5883 - 5894 (2007/10/02)
The optically active cyclohexenol derivatives 9a-9d, and 10a-10c are synthesized from (-)-6, which is obtained by enzymatic ester hydrolysis of racemic 8. Attempts towards the synthesis of the taxane skeleton are described.
