57448-92-7Relevant academic research and scientific papers
Controlled ring opening of N-sulfinyl- and N-silyl-N-carboxyanhydrides (NCA): One-pot synthesis of dipeptides and unsymmetrical peptidyl ureas from unprotected NCA
Mateos-Caro, Julia,Robin, Yves,Levacher, Vincent,Marsais, Francis
experimental part, p. 279 - 283 (2009/06/05)
We report herein new labile protecting groups of N-carboxyanhydrides (NCA) useful to prevent polymerization during coupling reactions with nitrogen nucleophiles. Thus, N-sulfinyl-NCA 1 and N-silyl-NCA 2 were prepared in situ and involved, without being is
