5745-35-7Relevant academic research and scientific papers
Rhodium-Catalyzed Synthesis of Dialkyl(Heteroaryl)Phosphine Sulfides by Phosphinylation of Heteroaryl Sulfides
Arisawa, Mieko,Tazawa, Takeru,Ichinose, Wataru,Kobayashi, Haruki,Yamaguchi, Masahiko
supporting information, p. 3488 - 3491 (2018/09/14)
Dialkyl(heteroaryl)phosphine sulfides were synthesized by the rhodium-catalyzed exchange reaction of heteroaryl aryl sulfides and tetraalkyldiphosphine disulfides. The reaction has a broad applicability, giving diverse dialkyl(heteroaryl)phosphine sulfides containing five- and six-membered heteroaryl groups. Various dialkyl(heteroaryl)phosphines were obtained by desulfurization. (Figure presented.).
Rhodium-catalyzed thiophosphinylation and phosphinylation reactions of disulfides and diselenides
Arisawa, Mieko,Ono, Tetsuya,Yamaguchi, Masahiko
, p. 5669 - 5671 (2007/10/03)
Alkyl and aryl dithiophosphinates were synthesized by the reaction of disulfides with biphosphine disulfides in the presence of RhH(PPh 3)4 and 1,2-diphenylphosphinoethane (dppe). The catalyst also promoted synthesis of thiophosphinates and selenothiophosphinates from disulfides and diselenides.
