57466-25-8Relevant academic research and scientific papers
Formation of 3-Aminophenols from Cyclohexane-1,3-diones
Szymor-Pietrzak, Damian,Khan, Muhammad N.,Pagès, Ana?s,Kumar, Ajay,Depner, Noah,Clive, Derrick L. J.
, p. 619 - 631 (2021)
meta-Aminophenols are formed by the action of DBU on 3-amino-2-chlorocyclohex-2-en-1-ones at room temperature in MeCN. The chloro compounds are generated by treating 3-aminocyclohex-2-en-1-ones with the easily prepared halogenating agent BnNMe3·ICl2 in Me
Syntheses of N-alkylated carbazolones via Pd(OAc)2-mediated intramolecular coupling of N-substituted 3-(arylamino)cyclohex-2-enones
Bi, Wenying,Yun, Xiliu,Fan, Yanfeng,Qi, Xiuxiang,Du, Yunfei,Huang, Jianhui
supporting information; experimental part, p. 2899 - 2904 (2011/02/25)
A variety of functionalized N-alkylated carbazolones were prepared via N-alkylation of 3-(arylamino)cyclohex-2-enones followed by an intramolecular oxidative coupling mediated by Pd(OAc)2 under an oxygen atmosphere. This approach adopts an inverted sequence, consisting of the conventional annulation and subsequent N-alkylation. Georg Thieme Verlag Stuttgart - New York.
