57519-81-0Relevant academic research and scientific papers
P-C Bond formation via direct and three-component conjugate addition catalyzed by 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD)
Jiang, Zhiyong,Zhang, Yan,Ye, Weiping,Tan, Choon-Hong
, p. 51 - 54 (2007)
The direct addition of P(O)-H bonds (dialkyl phosphites and diphenyl phosphonite) across various activated alkenes was catalyzed effectively by 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD). This is a mild, rapid and efficient protocol to generate P-C bonds.
Bronsted acid mediated nitrogenation of propargylic alcohols: An efficient approach to alkenyl nitriles
Huang, Xiaoqiang,Jiao, Ning
supporting information, p. 4324 - 4328 (2014/06/23)
A novel and efficient approach to alkenyl nitriles from readily available propargylic alcohols has been developed. This nitrogenation reaction is transition-metal-free and could be conducted under air at ambient temperature, which makes this protocol promising and practical. Moreover, NH4Br is disclosed as an efficient additive to promote the stereoselectivity of this reaction. the Partner Organisations 2014.
