57519-91-2Relevant articles and documents
C3H4Si species: Generation and matrix-spectroscopic identification of some silacyclobutadiene isomers
Maier, Guenther,Reisenauer, Hans Peter,Jung, Joerg,Pacl, Harald,Egenolf, Heiko
, p. 1297 - 1305 (2007/10/03)
Flash pyrolyses of four suitable precursors - namely 1,1,1-trimethyl-2-propargyldisilane (32), its allenyl (34) and propynyl isomer (35), as well as 2-ethynyl-1,1,1,2-tetramethyldisilane (31) - lead to the formation of three C3H4Si s
Silacyclopropyne: Matrix spectroscopic identification and ab initio investigations
Maier, Günther,Pacl, Harald,Reisenauer, Hans Peter,Meudt, Andreas,Janoschek, Rudolf
, p. 12712 - 12720 (2007/10/03)
Matrix-isolated 1-silacyclopropenylidene (7) has been generated by pulsed flash pyrolysis of 2-ethynyl-1,1,1-trimethyldisilane (4). By subsequent photolysis 7 can be isomerized into ethynylsilanediyl (5), vinylidene-silanediyl (8), and silacyclopropyne (9