57542-89-9Relevant academic research and scientific papers
Tuning of the structures of chiral phosphane-phosphites: Application to the highly enantioselective synthesis of α-acyloxy phosphonates by catalytic hydrogenation
Rubio, Miguel,Vargas, Sergio,Suarez, Andres,Alvarez, Eleuterio,Pizzano, Antonio
, p. 1821 - 1833 (2008/02/04)
A family of new chiral phosphane-phosphites 5 has been prepared and employed in the synthesis of rhodium complexes of formulation [Rh(cod)(5)]BF4 (7). The use of bulky phosphane or phosphite groups in the preparation of 7 avoids the formation of undesired
Mechanism-based design of a ROMP catalyst for sequence-selective copolymerization
Bornand, Marc,Chen, Peter
, p. 7909 - 7911 (2007/10/03)
(Chemical Equation Presented) Back and forth like a metronome is how the carbene moiety swings in a dual-site catalyst which produces a predominantly alternating copolymer of norbornene and cyclooctene from a one-pot reaction of appropriate mixtures of th
