57560-51-7

Upstream product

• 101-84-8 diphenylether 
• 199620-14-9 chromium⁽⁰⁾ hexacarbonyl 
• 12082-05-2 (η6-fluorobenzene)tricarbonylchromium 
• 139-02-6 sodium phenoxide 

Downstream Products

• 101680-46-0 ortho-methyldiphenylethertricarbonylchromium 
• 116449-56-0 (CH₃)3CCO₂CHCH₃C₆H₅Cr(CO)3 
• 2901-11-3 ester tertiobutylique de l'acide phenyl-2 propionique 
• 161434-24-8 tricarbonyl[η(6)-2-phenoxy(trimethylsilyl)benzene]chromium 
• 116449-62-8 C₆H₅C(C₆H₅)S(CH₂)3SCr(CO)3 

Relevant academic research and scientific papers

Mono-, bi- and polynuclear complexes of dimethyldiphenylsilane, diphenylether and biphenyl with Cr, Co and Ru. Synthesis and 1H, 13C, 17O and 29Si NMR spectroscopic characterization

Mono- and bimetallic transition metal carbonyls of dimethyldiphenylsilane, Ph2Si(CH3)2 (L1), diphenylether, Ph2O (L2) and biphenyl, Ph2 (L3): Ph2Si(CH3)2Cr(CO)3 (1), Ph2Si(CH3)22 (2), Ph2Si(CH3)2Co4(CO)9 (3), Ph2Si(CH3)22 (4), Ph2Si(CH3

Substitution nucleophile aromatique ipso et tele en serie arenetricarbonylchrome

A new nucleophilic aromatic substitution is desribed in the case of diphenylethertricarbonylchromium complexes.The overall sequence of the reaction consists in a regioselective meta substitution of the phenoxy group by the nucleophile: this is a tele-substitution.The ipso-substitution, known with halogenobenzenetricarbonylchromium complexes has been generalized in the case of diphenylethertricarbonylchromium complexes.