57566-16-2Relevant academic research and scientific papers
KINETICS AND MECHANISM OF THE MONOMOLECULAR HETEROLYSIS OF INDUSTRIAL ORGANOHALOGEN COMPOUNDS. XIII. NATURE OF SALT EFFECTS IN THE DEHYDROBROMINATION OF 7α-BROMOCHOLESTEROL BENZOATE IN γ-BUTYROLACTONE, NITROBENZENE, AND o-XYLENE
Ponomarev, N. E.,Dvorko, G. F.
, p. 388 - 400 (2007/10/02)
By the verdazyl method we studied the influence of salts on the rate of heterolysis of 7α-bromocholesterol benzoate in γ-butyrolactone, nitrobenzene, and o-xylene, v = k.It was shown that the rate of the heterolysis of 7β-bromocholesterol benzoate in these solvents is higher than the rate of the heterolysis of the α epimer by factors of 7, 12, and 110 respectively.
