57598-91-1Relevant academic research and scientific papers
The preparation of methyl (E)- and (Z)-O-methylbenzothiohydroximates
Johnson, James E.,Canseco, Diana C.,Rowe, Jeffrey E.
, p. 549 - 552 (2007/10/03)
A series of methyl (Z)-O-methylbenzothiohydroximates were prepared either by reaction of the corresponding (Z)-N-methoxybenzenecarboximidoyl bromides with potassium fluoride in dimethyl sulfoxide, or by reaction of N-methoxybenzamides with Lawesson's reag
The Preparation of Imidoyl Fluorides
Rowe, Jeffrey E.,Lee, Kam,Dolliver, Debra D.,Johnson, James E.
, p. 807 - 812 (2007/10/03)
The first general synthesis of imidoyl fluorides is reported here. Irradiation of the initially formed Z isomers of N-methoxybenzenecarboximidoyl fluorides led to a photoequilibrium containing both the E and Z isomers. The pure E isomers were able to be isolated from these isomeric mixtures. The n.m.r. spectra of these isomers are discussed.
