576-85-2Relevant academic research and scientific papers
Electrophilic fluorination of aromatic compounds with NF type reagents: Kinetic isotope effects and mechanism
Borodkin, Gennady I.,Zaikin, Pavel A.,Shubin, Vyacheslav G.
, p. 2639 - 2642 (2006)
H/D Isotope effects in fluorination of aromatic compounds with NF type reagents have been studied to reveal the reaction mechanism. The results obtained are consistent with a polar SEAr mechanism. Small deuterium isotope effects (kH/
Mechanism of electrophilic fluorination of aromatic compounds with NF-reagents
Borodkin,Zaikin,Shakirov,Shubin
, p. 1451 - 1459 (2008/09/16)
Kinetic isotope effects H/D in electrophilic fluorination of aromatic compounds with NF-reagents were investigated. The small values of k H/k D (0.86-1.00) are in agreement with the polar reaction mechanism where the Wheland complex
