57719-66-1Relevant academic research and scientific papers
Reaction of Chiral Cyclopropyl Halides with SmI2
Walborsky, H. M.,Topolski, Marek
, p. 370 - 373 (2007/10/02)
Reductions of (S)-(+)-1-bromo-1-methyl-2,2-diphenylcyclopropane (7), (S)-(+)-1-bromo-1-(methoxymethyl)-2,2-diphenylcyclopropane (19), and (R)-(-)-1-fluoro-1-iodo-2,2-diphenylcyclopropane (11) with samarium(II) iodide is reported.Evidence for a samarium(III) intermediate in the reaction is presented.
Formation of a Chiral 1-Fluoro-2,2-diphenylcyclopropyl Radical in the Barton Decarboxylation Reaction
Gawronska, K.,Gawronski, J.,Walborsky, H. M.
, p. 2193 - 2197 (2007/10/02)
The chiral 1-fluoro-2,2-diphenylcyclopropyl radical (8), generated in the Barton decarboxylation reaction, was used as a probe to evaluate a variety of halogen and hydrogen atom donating reagents as radical traps
