57740-63-3Relevant articles and documents
Fungal Pigments, 49. - Synthesis of Grevillins and Related 2H-Pyran-2,5(6H)-diones
Lohrisch, Hans-Joachim,Kopanski, Lothar,Herrmann, Rupert,Schmidt, Holger,Steglich, Wolfgang
, p. 177 - 194 (2007/10/02)
A convergent synthesis of grevillins 1 starts from diazoesters 6 which are converted into 3-aryl-2-oxopropyl ethyl oxalates 4 via bromoketones 7.Cyclization of 4 leads to pyrandiones 2 which are condensed with aromatic aldehydes to yield 4-aryl-2-benzylid