57752-05-3Relevant academic research and scientific papers
A rational approach towards the nucleophilic substitutions of alcohols "on water"
Cozzi, Pier Giorgio,Zoli, Luca
supporting information; experimental part, p. 4162 - 4166 (2009/03/11)
(Chemical Equation Presented) Walking on water: Which alcohols react with nucleophiles on the surface of water? The correlations introduced by Mayr et al., in which electrophiles are characterized by the parameter E, gives practical indications about the reactivity of alcohols with nucleophiles in pure water. Stable carbocations generated from the alcohols and characterized by E -2.5 readily react with nucleophiles in pure water at 80°C, without added Bronsted or Lewis acids.
Montmorillonite K10 clay catalysed Baeyer condensation of heterocyclic aldehydes with N,N-dimethylaniline: Synthesis and photo irradiation studies of heteroaryldiarylmethanes
Shanmuga,Varma
, p. 1258 - 1263 (2007/10/03)
The montmorillonitemK10 clay catalysed Baeyer condensation of a number of aromatic heterocyclic aldehydes (1-7) with N,N-dimethylaniline affords novel triarylmethanes (8-14) in good yield. The triarylmethane 8 was irradiated at 325 nm for 1 hr under different solvent systems and the photoproducts were identified as 15 and 16.
