57768-36-2Relevant academic research and scientific papers
The stereochemically controlled synthesis of spirocyclic ethers and lactones with medium-sized (7-, 8-, and 12-membered) carbocyclic rings by phenylthio migration: 1-oxaspiro[4. n]alkanes and alkan-2-ones with N = 6, 7, and 11
Chibale, Kelly,Hartley, Richard C.,Jenkins, Kevin P.,Simons, Matthew,Warren, Stuart,Richards, Ian C.
, p. 6783 - 6786 (2007/10/02)
3-Methyl-4-phenylthio-1-oxaspiro[4.6]undecanes, [4.7]dodecanes, [4.11]hexadecanes and the corresponding 2-ones (lactones) can be made from cyclohepta-, octa-, and dodecanone by chain extension to the 2-phenylthio-carbaldehyde, stereoselective aldol reacti
Additive Pummerer reactions of vinylic sulphoxides. Synthesis of 2-(phenylsulphenyl) aldehydes and primary alcohols
Craig,Daniels,MacKenzie
, p. 6973 - 6976 (2007/10/02)
Reaction in acetic anhydride solution of α,β-unsaturated sulphoxides 1 with sodium acetate and triflic anhydride gives 2-(phenylsulphenyl) acylals 4. Basic methanolysis of 4 gives 2-(phenylsulphenyl) aldehydes 8, whilst reduction gives directly 2-(phenylsulphenyl) primary alcohols 9.
