57794-09-9

Upstream product

• 2053-00-1 2,6-dideoxy-D-xylo-hexose 
• 108-24-7 acetic anhydride 
• 155154-09-9 (2R,3S,4S)-hept-6-ene-2,3,4-triol 

Downstream Products

• 862731-40-6 phenyl 3,4-di-O-acetyl-2-deoxy-1-thio-L-rhamnopyranoside 
• 1616283-69-2 methyl 2,3-di-O-benzyl-6-O-(3,4-di-O-acetyl-2-deoxy-β-L-rhamnopyranosyl)-α-D-glucopyranoside 
• 1616283-84-1 methyl 2,3-di-O-benzyl-6-O-(3,4-di-O-acetyl-2-deoxy-α-L-rhamnopyranosyl)-α-D-glucopyranoside 
• 1616283-70-5 methyl 2,3-di-O-benzyl-6-O-(3,4-di-O-acetyl-2-deoxy-β-L-rhamnopyranosyl)-α-D-mannopyranoside 
• 1616283-85-2 methyl 2,3-di-O-benzyl-6-O-(3,4-di-O-acetyl-2-deoxy-α-L-rhamnopyranosyl)-α-D-mannopyranoside 
• 1616283-71-6 phenyl 1-thio-2,3-di-O-benzyl-6-O-(3,4-di-O-acetyl-2-deoxy-β-L-rhamnopyranosyl)-β-D-glucopyranoside 
• 1616283-86-3 phenyl 1-thio-2,3-di-O-benzyl-6-O-(3,4-di-O-acetyl-2-deoxy-α-L-rhamnopyranosyl)-β-D-glucopyranoside 
• 135197-78-3 3,4-di-O-acetyl-2,6-dideoxy-1-phenylthio-α-L-arabino-pyranoside 
• 135197-79-4 phenyl 3,4-di-O-acetyl-2-deoxy-1-thio-β-L-rhamnopyranoside 

Relevant academic research and scientific papers

Indium-Mediated Allylation of Aldehydes: A Convenient Route to 2-Deoxy and 2,6-Dideoxy Carbohydrates

The allylation of protected polyhydroxy aldehydes 1 and 14 has been achieved by indium metal with ultrasound promotion generating the diastereomeric pair of homoallylic polyols 3, 4 and 16, 17 respectively with moderate to good stereoselectivity.Pursuing this allylation strategy with the corresponding deprotected polyhydroxy aldehydes led to the same pair of homoallylic polyols but with a quite different ratio of the diastereomers generated.The polyols were further transformed to 2-deoxy (5 and 6) and 2,6-dideoxy (18 and 19) carbohydrates by ozonolysis.