578008-77-2Relevant academic research and scientific papers
Synthesis, characterization, and crystal structure of platinum(II) and palladium(II) chlorides with an acidic α-diimine ligand
Buffin, Brian P.,Kundu, Abhijit
, p. 680 - 684 (2003)
Reaction of the symmetrical α-diimine ligand L with either PtCl2 or PdCl2(C6H5CN)2 affords the square planar d8 complexes 1 and 2, respectively. Both complexes were characterized by NMR spectroscopy and elemental analysis. The solid-state structure of 1, which crystallized in the triclinic space group P1 with unit cell parameters a = 8.688(2) A?, b = 13.840(2) A?, c = 14.136(2) A?, α = 111.346(14)°, β = 103.82(2)°, and γ = 102.69(2)°, was established by X-ray crystallography.
