57803-92-6Relevant academic research and scientific papers
[Pd]-Catalyzed Intermolecular Coupling and Acid Mediated Intramolecular Cyclodehydration: One-Pot Synthesis of Indenes
Niharika, Pedireddi,Satyanarayana, Gedu
supporting information, p. 971 - 979 (2018/02/22)
An efficient one-pot synthesis of indenes from simple starting materials is presented. This process involves a dual C–C bond formation through an intermolecular Heck coupling reaction followed by acid-mediated intramolecular cyclodehydration. The strategy
Palladium-catalysed direct cross-coupling of secondary alkyllithium reagents
Vila, Carlos,Giannerini, Massimo,Hornillos, Valentin,Fananas-Mastral, Martin,Feringa, Ben L.
, p. 1361 - 1367 (2014/03/21)
Palladium-catalysed cross-coupling of secondary C(sp3) organometallic reagents has been a long-standing challenge in organic synthesis, due to the problems associated with undesired isomerisation or the formation of reduction products. Based on our recently developed catalytic C-C bond formation with organolithium reagents, herein we present a Pd-catalysed cross-coupling of secondary alkyllithium reagents with aryl and alkenyl bromides. The reaction proceeds at room temperature and on short timescales with high selectivity and yields. This methodology is also applicable to hindered aryl bromides, which are a major challenge in the field of metal catalysed cross-coupling reactions.
BIPHENYL INTEGRIN ANTAGONISTS
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Page/Page column 38-39, (2010/11/08)
The following invention is directed to pharmaceutical compounds and compositions of the Formula (I). useful for treating conditions mediated by αVβ3 and/or αVβ5 integrin.
The effect of meta- and para-methoxy substitution on the reactivity of the radical cations of arylalkenes and alkanes. Radical ions in photochemistry. Part 26
Arnold, Donald R.,Du, Xinyao,Henseleit, Kerstin M.
, p. 839 - 852 (2007/10/02)
The effect of meta- and para-methoxy substitution on the reactivity of some radical cations has been determined.The compounds chosen for study were 1-(3-methoxyphenyl)-1-phenylethylene (7), 1-(4-methoxyphenyl)-1-phenylethylene (8), 3-(3-methoxyphenyl)inde
