578722-30-2Relevant academic research and scientific papers
[2,3]-Sigmatropic rearrangements of 3-sulfinyl dihydropyrans: application to the syntheses of the cores of ent-dysiherbaine and deoxymalayamicin A
De La Pradilla, Roberto Fernandez,Lwoff, Nadia,Del Aguila, Miguel Angel,Tortosa, Mariola,Viso, Alma
supporting information; experimental part, p. 8929 - 8941 (2009/04/05)
(Chemical Equation Presented) The [2,3]-sigmatropic rearrangement of a variety of configurationally stable diastereomeric allylic sulfinyl dihydropyrans, produced by base-promoted cyclization of sulfinyl dienols, has been studied. In some cases, the effic
Formal synthesis of ent-dysiherbaine from sulfinyl dihydropyrans by sigmatropic rearrangement and tethered aminohydroxylation
Fernández de la Pradilla, Roberto,Lwoff, Nadia,Viso, Alma
, p. 8141 - 8144 (2008/03/13)
A stereospecific [2,3]-sigmatropic rearrangement of a sulfinyl dihydropyran, followed by a tethered aminohydroxylation reaction, are the key steps of a formal synthesis of ent-dysiherbaine from an enantiopure sulfinyl dienol.
Pd-catalyzed sulfinylzincation of activated alkynes with 1-alkynyl sulfoxides as a sulfinyl source
Maezaki, Naoyoshi,Yagi, Suguru,Yoshigami, Ryoko,Maeda, Jun,Suzuki, Tomoko,Ohsawa, Shizuka,Tsukamoto, Kouji,Tanaka, Tetsuaki
, p. 5550 - 5558 (2007/10/03)
Unprecedented Pd-catalyzed sulfinylzincation with 1-alkynyl sulfoxide as a sulfinyl source was developed. Bis-sulfinyl alkenes were formed in good yields on treatment of 1-alkynyl sulfoxides with Et2Zn in the presence of a Pd-catalyst, wherein
