578740-38-2Relevant academic research and scientific papers
Nonvolatile Me3P-like P-donor ligand: Synthesis and properties of 4-phenyl-1-phospha-4-silabicyclo[2.2.2]octane
Ochida, Atsuko,Hara, Kenji,Ito, Hajime,Sawamura, Masaya
, p. 2671 - 2674 (2007/10/03)
(Matrix presented) A new trialkylphosphine ligand with Me 3P-like steric and electronic properties, 4-phenyl-1-phospha-4-silabicyclo[2.2.2]octane (Ph-SMAP), was synthesized. Given a phenyl group at the silicon atom, the Ph-SMAP ligand displayed nonvolatility with retention of Me3P-like properties. The new ligand was air-stable, crystalline, and easy to handle.
