57934-30-2Relevant articles and documents
Behavior of allylamines in the system KOH-DMSO
Musorin
, p. 915 - 918 (2007/10/03)
Isomerization of triallylamine in the system KOH-DMSO at 90-100°C leads to formation of tris(1-propenyl)amine in quantitative yield. Under similar conditions, diallyl(ethyl)amine is converted into ethylbis(1-propenyl)amine and 1-ethyl-3-methylcyclohexane. Diallylamine in KOH-DMSO gives rise to a complex mixture of products consisting of bis(1-propenyl)amine, methylbis(1-propenyl) amine, 1-ethyl-3-methylcyclohexane, and 2-ethyl-3,5-dimethylpiperidine. Ways of formation of these products are discussed.