579505-86-5

Upstream product

• 579505-80-9 tert-butyl-(4-methoxy-2,2-dimethyl-6-trityloxymethyl-dihydro-furo[3,4-d][1,3]dioxol-3a-ylmethoxy)-diphenyl-silane 
• 579505-82-1 tert-butyl-(6-iodomethyl-4-methoxy-2,2-dimethyl-dihydro-furo[3,4-d][1,3]dioxol-3a-ylmethoxy)-diphenyl-silane 
• 579505-81-0 [6a-(tert-butyl-diphenyl-silanyloxymethyl)-6-methoxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-methanol 
• 579505-84-3 1-[(4S,5R)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-5-vinyl-[1,3]dioxolan-4-yl]-prop-2-en-1-ol 
• 579505-83-2 (4R,5R)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-5-vinyl-[1,3]dioxolane-4-carbaldehyde 
• 114474-98-5 2-C-hydroxymethyl-2,3-O-isopropylidene-5-O-trityl-α,β-D-ribofuranose 
• 54503-64-9 2,3-O-isopropylidene-5-O-trityl-D-ribofuranose 
• 67814-68-0 2,3-O-isopropylidene-D-ribofuranose 
• 579505-85-4 3a-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-4,6a-dihydro-3aH-cyclopenta[1,3]dioxol-4-ol 

Downstream Products

• 57236-37-0 (+)-pentenomycin 
• 66655-93-4 (+/-)-dehydropentenomycin 

Relevant academic research and scientific papers

A common and versatile synthetic route to (-) and (+) pentenomycin I, (+) halopentenomycin i and dehydropentenomycin

A versatile and stereoselective total synthesis of (+) and (-) pentenomycin I, (+) halopentenomycins I and dehydropentenomycin from a common chiral polyhydroxylated cyclopentene through oxidation and protection/deprotection has been described. Stereoselec

Stereoselective synthesis of (-)- and (+)-pentenomycins using RCM

An efficient synthesis of enantiopure (-)- and (+)-pentenomycins are described by reductive iodo elimination and ring-closing metathesis (RCM), as the key steps. The first synthesis of the unnatural (+)-isomer is described.