57951-38-9Relevant academic research and scientific papers
Behavior of allylamines in the system KOH-DMSO
Musorin
, p. 915 - 918 (2003)
Isomerization of triallylamine in the system KOH-DMSO at 90-100°C leads to formation of tris(1-propenyl)amine in quantitative yield. Under similar conditions, diallyl(ethyl)amine is converted into ethylbis(1-propenyl)amine and 1-ethyl-3-methylcyclohexane. Diallylamine in KOH-DMSO gives rise to a complex mixture of products consisting of bis(1-propenyl)amine, methylbis(1-propenyl) amine, 1-ethyl-3-methylcyclohexane, and 2-ethyl-3,5-dimethylpiperidine. Ways of formation of these products are discussed.
Unexpected transformations of alkyldiallylamines in the KOH-DMSO system
Musorin
, p. 1576 - 1577 (2007/10/03)
Triallylamine in the KOH-DMSO system readily isomerizes into tri(1-propenyl)amine. Alkyldiallylamines in the same system give 1-ethyl-3-methylcyclohexane along with alkyldi(1-propenyl)amine. The effect of quantity of base and reaction temperature on product ratio was studied. A route of 1-ethyl-3-methyl-cyclohexane formation was proposed.
