58016-15-2Relevant academic research and scientific papers
Acid-promoted reaction of cyclic allylic diols with carbonyl compounds. Stereoselective ring-enlarging tetrahydrofuran annulations
Brown, Mark J.,Harrison, Timothy,Herrinton, Paul M.,Hopkins, Mark H.,Hutchinson, Kira D.,Mishra, Pratibha,Overman, Larry E.
, p. 5365 - 5378 (2007/10/02)
A wide variety of cis-fused hexahydrocyclopenta[b]furan-4-ones (3, n = 0), hexahydro-4(2H)-benzofuranones (3, n = 1), and octahydrocyclohepta[b]furan-4-ones (3, n = 2) can be prepared with high levels of stereocontrol by the title reaction. The scope and
Ring-Enlarging Furan Annulations
Herrinton, Paul M.,Hopkins, Mark H.,Mishra, Pratibha,Brown, Mark J.,Overman, Larry E.
, p. 3711 - 3712 (2007/10/02)
Substituted cycloheptatetrahydrofurans and octahydrofurans are formed with high levels of stereocontrol by acid-promoted rearrangement of acetals derived from 1-alkenyl-2-hydroxycyclohexanols and 1-alkenyl-2-hydroxycyclopentanols, respectively.In some cas
