5806-59-7

Basic information

• Product Name: MESITYLLITHIUM
• Synonyms: MESITYLLITHIUM
• CAS NO: 5806-59-7
• Molecular Formula: C₉H₁₁Li
• Molecular Weight: 126.12
• Mol File: 5806-59-7.mol
• Article Data: 10

Chemical Properties

• Appearance: /
• CAS DataBase Reference: MESITYLLITHIUM(CAS DataBase Reference)
• NIST Chemistry Reference: MESITYLLITHIUM(5806-59-7)
• EPA Substance Registry System: MESITYLLITHIUM(5806-59-7)

Safety Data

• Hazardous Substances Data: 5806-59-7(Hazardous Substances Data)

Upstream product

• 576-83-0 2,4,6-trimethylphenyl bromide 
• 109-72-8 n-butyllithium 

Downstream Products

• 111089-28-2 Mesityl-phenyl-[2]pyridyl-methanol 
• 20685-14-7 Mesityl-diphenyl-methanol 
• 102590-48-7 9-(2,4,6-trimethyl-phenyl)-phenanthrene 
• 59660-68-3 α,α,2,4,6-pentamethylbenzenemethanol 
• 16260-22-3 Sn{2,4,6-trimethyl-phenyl}4 
• 3355-51-9 2,2',4,4',6,6'-Hexamethyl-α,α'-difluorostilben 
• 65481-78-9 B-mesityl-9-borabicyclo[3.3.1]nonane 
• 84061-27-8 E-1-mesityl-2-methyl-2-buten-1-ol 
• 2700-84-7 2,2-dimethyl-1-(2,4,6-trimethylphenyl)propan-1-one 
• 91873-91-5 1-mesityl-3,3-dimethyl-butane-1,2-dione 
• 108-67-8 1,3,5-trimethyl-benzene 
• 99342-81-1 5,5-dimesityl-3,3-dimethyl-5-hydroxypentanoic acid lactone 
• 91475-77-3 N-(2,4,6-trimethylbenzyl)phenylamine 
• 108202-49-9 difluoromesitylsilane 

Relevant articles and documents

Boron-substituted 1,3-dihydro-1,3-azaborines: Synthesis, structure, and evaluation of aromaticity

Getting the family together: A general synthetic strategy based on nucleophilic substitution provided B-substituted 1,3-dihydro-1,3-azaborines (see scheme), BN isosteres of arenes with potential for application in biomedicine and materials science. Experi

Neutral Fe(iv) alkylidenes, including some that bind dinitrogen

Neutral, formally Fe(iv) alkylidene species are sought as plausible olefin metathesis catalysts, and the synthesis of several is described herein. The complexes are prepared via nucleophilic attack (Nu = MeLi, PhCH2K, 2-picolyllithium, Me2PCH2Li, MePhPCH2Li, Ph2PCH2Li) at the imine of cationic [mer-{κ-C,N,C-(C6H4-yl)-2-CH=N(2-C6H4-C(iPr)=)}Fe(PMe3)3][B(3,5-CF3-C6H3)4]. In contrast, MeMgCl and mesityllithium displaced and deprotonated bound PMe3, respectively. Structural details are provided for mer-{κ-C,N,C-(C6H4-yl)-2-CH(Bn)N(2-C6H4-C(iPr)=)}Fe{trans-(PMe3)2}N2 and {κ-C,N,C,P-(C6H4-yl)-2-CH(CH2PMe2)N(2-C6H4-C(iPr)=)}Fe(PMe3)2.

Highly selective one-pot synthesis of spirophosphoranes exhibiting reversed apicophilicity by oxidation of dianions generated from P-H spirophosphorane

(formula presented) Mild and highly selective one-pot procedures for obtaining phosphoranes that exhibit reversed (O-cis) apicophilicity are described. On the basis of the procedures, O-cis phosphorane bearing an aryl group (R = 2,4,6-tri-i-propylphenyl)