5809-07-4Relevant academic research and scientific papers
High chemo and regioselective formation of alcohols from the hydrocarbonylation of alkenes using cooperative ligand effects
Boogaerts, Ine T.I. F.,White, Daniel F. S.,Cole-Hamilton, David J.
supporting information; experimental part, p. 2194 - 2196 (2010/07/08)
The hydrocarbonylation of alkenes, including allyl alcohol, catalysed by rhodium complexes and wide angle bidentate ligands together with PEt 3, gives alcohols as the primary products with high chemo and regio-selectivity.
Catalytic oxidation of furan and hydrofuran compounds. 5. Hydroxy- and ethoxydihydrofurans and ethoxyfuran - New products from the reaction of furan with hydrogen peroxide
Poskonin,Badovskaya,Povarova
, p. 900 - 906 (2007/10/03)
It was established for the first time by chromato-mass spectrometry that 2-X-5-Y-2,5-dihydrofurans (X, Y = OH, OEt) and 2-ethoxyfuran are formed during the oxidation of furan by hydrogen peroxide in a mixture of water and ethanol in the presence of VOSO4. Stable tautomeric forms of 2-hydroxy- and 2,5-dihydroxyfurans - 2(5H)-furanone and 5-ethoxy-2(5H)-furanone respectively - were isolated from the reaction mixture. A probable scheme for the main reaction paths is proposed. 1999 Kluwer Academic/Plenum Publishers.
