581069-58-1Relevant academic research and scientific papers
Medium-sized cyclophanes, 62. Synthesis and structure of [2.2]metacyclophane-1,2-diol and conversion into [2.2]metacyclophane-1,2-dione by Swern oxidation
Yamato, Takehiko,Hironaka, Toru,Saisyo, Tatsunori,Manabe, Tomoki,Okuyama, Ken-ichiro
, p. 277 - 288 (2007/10/03)
McMurry cyclization of 1,2-bis(5-t-butyl-2-methyl-3-formylphenyl)ethane 2 afforded anti-[2.2]metacyclophan-1-ene 3 and anti-[2.2]metacyclophane-1,2-diols 4, which were converted into the corresponding 1,2-dione 6 by Swern oxidation.
