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Diphenyliodonium hexafluorophosphate
Cas No: 58109-40-3
USD $ 190.0-200.0 / Gram 20 Gram 30 Metric Ton/Year Guarson Chemical Co., Ltd. Contact Supplier
Diphenyliodonium hexafluorophosphate
Cas No: 58109-40-3
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
Diphenyliodonium hexafluorophosphate
Cas No: 58109-40-3
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High Quality Oled CAS 58109-40-3 Diphenyliodonium hexafluorophosphate
Cas No: 58109-40-3
USD $ 0.1-0.1 / Gram 1 Gram 100 Metric Ton/Year Xi'an Xszo Chem Co., Ltd. Contact Supplier
Amadis Chemical offer CAS#58109-40-3;CAT#A831742
Cas No: 58109-40-3
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Iodonium Diphenyl Hexafluorophosphate
Cas No: 58109-40-3
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Diphenyliodonium hexafluorophosphate 58109-40-3
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Diphenyliodonium hexafluorophosphate
Cas No: 58109-40-3
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High Purity Diphenyliodonium hexafluorophosphate Cas No: 58109-40-3
Cas No: 58109-40-3
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58109-40-3 Usage

Uses

Catalyst for the photochemical polymerization of various monomers.
InChI:InChI=1/C12H10I.F6P/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;1-7(2,3,4,5)6/h1-10H;/q+1;-1

58109-40-3 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
TCI America (D2238)  Diphenyliodonium Hexafluorophosphate  >97.0%(T) 58109-40-3 1g 290.00CNY Detail
TCI America (D2238)  Diphenyliodonium Hexafluorophosphate  >97.0%(T) 58109-40-3 5g 790.00CNY Detail
TCI America (D2238)  Diphenyliodonium Hexafluorophosphate  >97.0%(T) 58109-40-3 25g 3,250.00CNY Detail
Alfa Aesar (A17934)  Diphenyliodonium hexafluorophosphate, 98%    58109-40-3 10g 879.0CNY Detail
Alfa Aesar (A17934)  Diphenyliodonium hexafluorophosphate, 98%    58109-40-3 50g 3257.0CNY Detail
Alfa Aesar (A17934)  Diphenyliodonium hexafluorophosphate, 98%    58109-40-3 250g 12247.0CNY Detail
Aldrich (548014)  Diphenyliodoniumhexafluorophosphate  ≥98% 58109-40-3 548014-5G 1,384.11CNY Detail
Aldrich (548014)  Diphenyliodoniumhexafluorophosphate  ≥98% 58109-40-3 548014-25G 5,269.68CNY Detail

58109-40-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name Diphenyliodonium hexafluorophosphate

1.2 Other means of identification

Product number -
Other names diphenyliodanium,hexafluorophosphate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:58109-40-3 SDS

58109-40-3Synthetic route

iodobenzene
591-50-4

iodobenzene

benzene
71-43-2

benzene

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

Conditions
ConditionsYield
With hexafluorophosphoric acid; 3-chloro-benzenecarboperoxoic acid
diphenyliodonium 4-nitrophenolate

diphenyliodonium 4-nitrophenolate

A

potassium 4-nitrophenolate
1124-31-8

potassium 4-nitrophenolate

B

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

Conditions
ConditionsYield
With potassium hexafluorophosphate In acetonitrile at 20℃; Equilibrium constant; Temperature; Inert atmosphere;
diphenyliodonium 4-nitrophenolate

diphenyliodonium 4-nitrophenolate

tert-butylammonium hexafluorophosphate(V)
3109-63-5

tert-butylammonium hexafluorophosphate(V)

A

tetra-n-butylammonium p-nitrophenoxide
3002-48-0

tetra-n-butylammonium p-nitrophenoxide

B

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

Conditions
ConditionsYield
In acetonitrile at 20℃; Equilibrium constant; Inert atmosphere;
(allylsulfonyl)benzene
16212-05-8

(allylsulfonyl)benzene

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

trans-cinnamyl phenyl sulfone
16212-07-0

trans-cinnamyl phenyl sulfone

Conditions
ConditionsYield
With palladium diacetate; sodium hydrogencarbonate In acetonitrile at 50℃; for 22h;99%
indole
120-72-9

indole

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

2-phenyl-indole
948-65-2

2-phenyl-indole

Conditions
ConditionsYield
Stage #1: indole With C64H56N6P2Pd2 In acetic acid at 24.84℃; for 0.0833333h; Inert atmosphere; Schlenk technique;
Stage #2: diphenyliodonium hexafluorophosphate In acetic acid at 24.84℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique;
99%
Stage #1: indole With Pd2[(C6H4)PPh2]2[O2CC6H5]2; acetic acid at 24.84℃; for 0.0833333h; Inert atmosphere; Schlenk technique;
Stage #2: diphenyliodonium hexafluorophosphate at 24.84℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique;
99%
5-methyl-2-pyridone
1003-68-5

5-methyl-2-pyridone

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

Pirfenidone
53179-13-8

Pirfenidone

Conditions
ConditionsYield
With triethylamine; copper(l) chloride In toluene at 20℃; for 0.5h; Inert atmosphere;99%
diphenyl sulfide
139-66-2

diphenyl sulfide

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

triphenylsulphonium hexafluorophosphate
57835-99-1

triphenylsulphonium hexafluorophosphate

Conditions
ConditionsYield
With copper(II) benzoate In chlorobenzene at 125℃; under 2068.65 Torr; for 0.0333333h; Inert atmosphere; Microwave irradiation;98%
1,2-diacetoxy-3-butene
18085-02-4

1,2-diacetoxy-3-butene

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

(E)-4-phenylbut-3-ene-1,2-diyl diacetate
119420-99-4

(E)-4-phenylbut-3-ene-1,2-diyl diacetate

Conditions
ConditionsYield
With palladium diacetate; sodium hydrogencarbonate In acetonitrile at 50℃; for 20h;98%
1-methylindole
603-76-9

1-methylindole

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

1-methyl-2-phenyl-1H-indole
3558-24-5

1-methyl-2-phenyl-1H-indole

Conditions
ConditionsYield
With Pd2[(C6H4)PPh2]2[CF3C(O)CHC(O)CF3]2 In acetic acid at 24.84℃; for 30h; Catalytic behavior; Reagent/catalyst; Time; Solvent; Inert atmosphere; Schlenk technique;98%
Stage #1: 1-methylindole With Pd2[(C6H4)PPh2]2[O2CC6H5]2; acetic acid at 24.84℃; for 0.0833333h; Inert atmosphere; Schlenk technique;
Stage #2: diphenyliodonium hexafluorophosphate at 24.84℃; for 10h; Reagent/catalyst; Inert atmosphere; Schlenk technique;
97%
2-(phenylthio)thioxanthone
1195763-38-2

2-(phenylthio)thioxanthone

potassium trifluorotris(pentafluoroethyl)phosphate
123215-04-3

potassium trifluorotris(pentafluoroethyl)phosphate

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

diphenyl-2-thioxanthonylsulfonium tris(pentafluoroethyl)trifluorophosphate

diphenyl-2-thioxanthonylsulfonium tris(pentafluoroethyl)trifluorophosphate

Conditions
ConditionsYield
Stage #1: 2-(phenylthio)thioxanthone; diphenyliodonium hexafluorophosphate With copper(II) benzoate In chlorobenzene at 120 - 125℃; for 3h;
Stage #2: potassium tris(pentafluoroethyl)trifluorophosphate In dichloromethane; water at 25℃; for 2h;
98%
Stage #1: 2-(phenylthio)thioxanthone; diphenyliodonium hexafluorophosphate With copper(II) benzoate In chlorobenzene at 120 - 125℃; for 3h;
Stage #2: potassium tris(pentafluoroethyl)trifluorophosphate In dichloromethane; water at 25℃; for 2h;
Stage #1: 2-(phenylthio)thioxanthone; diphenyliodonium hexafluorophosphate With copper(II) benzoate In chlorobenzene at 120 - 125℃; for 3h;
Stage #2: potassium tris(pentafluoroethyl)trifluorophosphate In dichloromethane; water at 25℃; for 2h;
1-(1H-inden-3-yl)cyclopentan-1-ol

1-(1H-inden-3-yl)cyclopentan-1-ol

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

2'-phenyl-2',3'-dihydrospiro[cyclohexane-1,1'-inden]-2-one

2'-phenyl-2',3'-dihydrospiro[cyclohexane-1,1'-inden]-2-one

Conditions
ConditionsYield
With 2,6-di-tert-butyl-pyridine; C23H22CuF6N2O8S2 In dichloromethane at 0 - 25℃; for 48h; Pinacol Rearrangement; Inert atmosphere; diastereoselective reaction;98%
1-(1H-inden-3-yl)cyclopentan-1-ol

1-(1H-inden-3-yl)cyclopentan-1-ol

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

(1S,2'R)-2'-phenyl-2',3'-dihydrospiro[cyclohexane-1,1'-inden]-2-one

(1S,2'R)-2'-phenyl-2',3'-dihydrospiro[cyclohexane-1,1'-inden]-2-one

Conditions
ConditionsYield
With 2,6-di-tert-butyl-pyridine; [Cu(OTf)2((R)-Ph-BOX)] In dichloromethane at 0 - 25℃; for 48h; Pinacol Rearrangement; Inert atmosphere; stereoselective reaction;98%
dibenzo-18-crown-6
14187-32-7

dibenzo-18-crown-6

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

diphenyliodonium hexafluorophosphate-dibenzo-18-crown-6 ether complex

diphenyliodonium hexafluorophosphate-dibenzo-18-crown-6 ether complex

Conditions
ConditionsYield
In ethyl acetate for 0.0833333h; Reflux;97.6%
(E)-(4-(2-(9,9-didecyl-7-nitro-9H-fluoren-2-yl)vinyl)phenyl)(phenyl)sulfane

(E)-(4-(2-(9,9-didecyl-7-nitro-9H-fluoren-2-yl)vinyl)phenyl)(phenyl)sulfane

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

(E)-(4-(2-(9,9-didecyl-7-nitro-9H-fluoren-2-yl)vinyl)phenyl)diphenylsulfonium hexafluorophosphate (V)

(E)-(4-(2-(9,9-didecyl-7-nitro-9H-fluoren-2-yl)vinyl)phenyl)diphenylsulfonium hexafluorophosphate (V)

Conditions
ConditionsYield
With copper(II) benzoate In chlorobenzene at 125℃; under 2068.65 Torr; Inert atmosphere; Microwave irradiation; Darkness;97%
tris(trifluoromethanesulfonyl)methide potassium salt
114395-69-6

tris(trifluoromethanesulfonyl)methide potassium salt

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

C4F9O6S3(1-)*C12H10I(1+)
182505-78-8

C4F9O6S3(1-)*C12H10I(1+)

Conditions
ConditionsYield
In ethyl acetate at 20℃; for 1h;97%
sodium benzenesulfonate
873-55-2

sodium benzenesulfonate

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

diphenyl sulphone
127-63-9

diphenyl sulphone

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 90℃; for 24h; Schlenk technique; Inert atmosphere;96%
diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

1-(3,4-dihydro-2H-pyran-6-yl)cyclopentan-1-ol
74938-47-9

1-(3,4-dihydro-2H-pyran-6-yl)cyclopentan-1-ol

(5R,10R)-10-phenyl-6-oxaspiro[4.5]decan-1-one

(5R,10R)-10-phenyl-6-oxaspiro[4.5]decan-1-one

Conditions
ConditionsYield
With 2,6-di-tert-butyl-pyridine; [Cu(OTf)2((R)-Ph-BOX)] In dichloromethane at 0 - 25℃; for 36h; Pinacol Rearrangement; Inert atmosphere; stereoselective reaction;96%
1-(5,6-dimethoxy-1H-inden-3-yl)cyclopentan-1-ol

1-(5,6-dimethoxy-1H-inden-3-yl)cyclopentan-1-ol

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

5',6'-dimethoxy-2'-phenyl-2',3'-dihydrospiro[cyclohexane-1,1'-inden]-2-one

5',6'-dimethoxy-2'-phenyl-2',3'-dihydrospiro[cyclohexane-1,1'-inden]-2-one

Conditions
ConditionsYield
With 2,6-di-tert-butyl-pyridine; C23H22CuF6N2O8S2 In dichloromethane at 0 - 25℃; for 48h; Pinacol Rearrangement; Inert atmosphere; diastereoselective reaction;96%
1-(5,6-dimethoxy-1H-inden-3-yl)cyclopentan-1-ol

1-(5,6-dimethoxy-1H-inden-3-yl)cyclopentan-1-ol

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

(1S,2'R)-5',6'-dimethoxy-2'-phenyl-2',3'-dihydrospiro[cyclohexane-1,1'-inden]-2-one

(1S,2'R)-5',6'-dimethoxy-2'-phenyl-2',3'-dihydrospiro[cyclohexane-1,1'-inden]-2-one

Conditions
ConditionsYield
With 2,6-di-tert-butyl-pyridine; [Cu(OTf)2((R)-Ph-BOX)] In dichloromethane at 0 - 25℃; for 48h; Pinacol Rearrangement; Inert atmosphere; stereoselective reaction;96%
(Z)-3-(1-((tert-butyldimethylsilyl)oxy)-5-phenylpent-1-en-1-yl)oxazolidin-2-one
1330660-53-1

(Z)-3-(1-((tert-butyldimethylsilyl)oxy)-5-phenylpent-1-en-1-yl)oxazolidin-2-one

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

(S)-3-(2,5-diphenylpentanoyl)oxazolidin-2-one
1330660-76-8

(S)-3-(2,5-diphenylpentanoyl)oxazolidin-2-one

Conditions
ConditionsYield
With [((CH3)2C(C3H3NOC6H5)2)Cu(OSO2CF3)]; CuOTf*1/2PhMe In dichloromethane; toluene at -10℃; for 24h; optical yield given as %ee; enantioselective reaction;95%
diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

benzonitrile
100-47-0

benzonitrile

phenylpropynoic acid ethyl ester
2216-94-6

phenylpropynoic acid ethyl ester

ethyl 2,4-diphenylquinoline-3-carboxylate
17282-90-5

ethyl 2,4-diphenylquinoline-3-carboxylate

Conditions
ConditionsYield
With copper(II) bis(trifluoromethanesulfonate) In 1,2-dichloro-ethane at 120℃; Inert atmosphere; Sealed tube; regioselective reaction;95%
diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

6-phenyl-5-hexyne-1-nitrile
152858-50-9

6-phenyl-5-hexyne-1-nitrile

9-phenyl-2,3-dihydro-1H-cyclopenta[b]quinoline
10265-82-4

9-phenyl-2,3-dihydro-1H-cyclopenta[b]quinoline

Conditions
ConditionsYield
With copper(II) bis(trifluoromethanesulfonate) In 1,2-dichloro-ethane at 130℃; for 12h; Inert atmosphere; Sealed tube;95%
(Z)-6-(tert-butyldimethylsilyloxy)-6-(2-oxooxazolidin-3-yl)hex-5-enyl benzoate
1330660-55-3

(Z)-6-(tert-butyldimethylsilyloxy)-6-(2-oxooxazolidin-3-yl)hex-5-enyl benzoate

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

(S)-6-oxo-6-(2-oxooxazolidin-3-yl)-5-phenylhexyl benzoate
1330660-78-0

(S)-6-oxo-6-(2-oxooxazolidin-3-yl)-5-phenylhexyl benzoate

Conditions
ConditionsYield
With [((CH3)2C(C3H3NOC6H5)2)Cu(OSO2CF3)]; (CuOTf)2PhMe In dichloromethane; toluene at 0℃; for 24h; optical yield given as %ee; enantioselective reaction;94%
N-(2-methylbenzoyl)-8-aminoquinoline
1182669-71-1

N-(2-methylbenzoyl)-8-aminoquinoline

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

2-methyl-N-phenyl-N-(quinolin-8-yl)benzamide

2-methyl-N-phenyl-N-(quinolin-8-yl)benzamide

Conditions
ConditionsYield
With copper(II) acetate monohydrate In 1,2-dichloro-ethane at 80℃; for 48h;94%
With copper(II) acetate monohydrate In 1,2-dichloro-ethane at 80℃; for 48h; Molecular sieve; Schlenk technique;94%
(Z)-benzyl (6-((tert-butyldimethylsilyl)oxy)-6-(2-oxooxazolidin-3-yl)hex-5-en-1-yl)(methyl)carbamate
1330660-56-4

(Z)-benzyl (6-((tert-butyldimethylsilyl)oxy)-6-(2-oxooxazolidin-3-yl)hex-5-en-1-yl)(methyl)carbamate

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

(S)-benzyl methyl(6-oxo-6-(2-oxooxazolidin-3-yl)-5-phenylhexyl)carbamate
1330660-79-1

(S)-benzyl methyl(6-oxo-6-(2-oxooxazolidin-3-yl)-5-phenylhexyl)carbamate

Conditions
ConditionsYield
With [((CH3)2C(C3H3NOC6H5)2)Cu(OSO2CF3)]; CuOTf*1/2PhMe In dichloromethane; toluene at 5℃; for 24h; optical yield given as %ee; enantioselective reaction;93%
N-methylisocarbostyril
4594-71-2

N-methylisocarbostyril

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

2-methyl-8-phenylisoquinolin-1(2H)-one

2-methyl-8-phenylisoquinolin-1(2H)-one

Conditions
ConditionsYield
With silver hexafluoroantimonate; bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] In acetic acid at 100℃; for 24h; Mechanism; Reagent/catalyst; Solvent; regiospecific reaction;93%
ethyl 2-acetoxy-3-butenoate
127700-79-2

ethyl 2-acetoxy-3-butenoate

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

(E)-ethyl 2-acetoxy-4-phenylbut-3-enoate
1151782-13-6

(E)-ethyl 2-acetoxy-4-phenylbut-3-enoate

Conditions
ConditionsYield
With resorcinolbis[(diphenyl)phosphinite] palladium trifluoroacetate; sodium hydrogencarbonate In acetonitrile at 50℃; for 19h;92%
3,5-dibromo-2-hydroxypyridine
13472-81-6

3,5-dibromo-2-hydroxypyridine

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

3,5-dibromo-1-phenylpyridin-2(1H)-one
120491-71-6

3,5-dibromo-1-phenylpyridin-2(1H)-one

Conditions
ConditionsYield
With triethylamine; copper(l) chloride In toluene at 20℃; for 0.0833333h; Inert atmosphere;92%
5-methyl-2-cyanoaniline
26830-96-6

5-methyl-2-cyanoaniline

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

2-(4-imino-7-methyl-3-phenyl-3,4-dihydroquinazolin-2-yl)-5-methylaniline

2-(4-imino-7-methyl-3-phenyl-3,4-dihydroquinazolin-2-yl)-5-methylaniline

Conditions
ConditionsYield
In 1,2-dichloro-ethane at 20 - 120℃; for 48h; Inert atmosphere;92%
diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

anthranilic acid nitrile
1885-29-6

anthranilic acid nitrile

(2-(3-phenyl)-4-imino-3,4-dihydroquinazoline)-2-aniline

(2-(3-phenyl)-4-imino-3,4-dihydroquinazoline)-2-aniline

Conditions
ConditionsYield
In 1,2-dichloro-ethane at 20 - 120℃; for 48h; Inert atmosphere;92%
methyl 3-(3,4-dihydro-2H-pyran-6-yl)-3-hydroxycyclobutane-1-carboxylate

methyl 3-(3,4-dihydro-2H-pyran-6-yl)-3-hydroxycyclobutane-1-carboxylate

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

methyl 4-oxo-10-phenyl-6-oxaspiro[4.5]decane-2-carboxylate

methyl 4-oxo-10-phenyl-6-oxaspiro[4.5]decane-2-carboxylate

methyl 4-oxo-10-phenyl-6-oxaspiro[4.5]decane-2-carboxylate

methyl 4-oxo-10-phenyl-6-oxaspiro[4.5]decane-2-carboxylate

Conditions
ConditionsYield
With 2,6-di-tert-butyl-pyridine; C23H22CuF6N2O8S2 In dichloromethane at 0 - 25℃; for 48h; Pinacol Rearrangement; Inert atmosphere; diastereoselective reaction;A 92%
B 7%
(Z)-3-(1-(tert-butyldimethylsilyloxy)-6-methoxyhex-1-enyl)oxazolidin-2-one
1330660-49-5

(Z)-3-(1-(tert-butyldimethylsilyloxy)-6-methoxyhex-1-enyl)oxazolidin-2-one

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

(S)-3-(6-methoxy-2-phenylhexanoyl)oxazolidin-2-one
1330660-72-4

(S)-3-(6-methoxy-2-phenylhexanoyl)oxazolidin-2-one

Conditions
ConditionsYield
With [((CH3)2C(C3H3NOC6H5)2)Cu(OSO2CF3)]; (CuOTf)2PhMe In dichloromethane; toluene at 0℃; for 24h; optical yield given as %ee; enantioselective reaction;91%
pyridine N-oxide
694-59-7

pyridine N-oxide

diphenyliodonium hexafluorophosphate
58109-40-3

diphenyliodonium hexafluorophosphate

2-(pyridin-1-ium-1-yl)phenolate

2-(pyridin-1-ium-1-yl)phenolate

Conditions
ConditionsYield
Stage #1: pyridine N-oxide; diphenyliodonium hexafluorophosphate In 1,2-dichloro-ethane at 120℃; for 48h; Inert atmosphere; Schlenk technique;
Stage #2: With potassium carbonate In methanol; 1,2-dichloro-ethane at 20℃; for 1h;
91%
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