58194-61-9Relevant academic research and scientific papers
A practical screening strategy of arsenic ligands for a transition-metal-catalyzed reaction
Imoto, Hiroaki,Yamazawa, Chieko,Tanaka, Susumu,Kato, Takuji,Naka, Kensuke
, p. 821 - 823 (2017)
Organoarsenic ligands were synthesized via a safe and easy procedure, superior to the conventional synthetic methodologies. Diiodophenylarsine was prepared in situ, and was readily converted to diarylphenylarsines. Pd-catalyzed Mizoroki-Heck reaction was investigated using the obtained arsenic ligands. It was found that bulky and electron-donating ligands were effective for the reaction, meaning that the success in the screening of arsenic ligand structures was based on the present facile strategy.
