58207-39-9

Usage

Uses

Used in Pharmaceutical Industry:
Myrrhine is used as a pharmaceutical compound for its potential medicinal properties and therapeutic applications.
Used in Cosmetic Industry:
Myrrhine is used as an ingredient in cosmetic products for its beneficial effects on skin health and appearance.
Used in Food Industry:
Myrrhine is used as a flavoring agent or additive in certain food products to enhance taste and provide unique characteristics.
(Note: The specific applications and industries for Myrrhine are not provided in the materials, so the above uses are hypothetical and should be verified with further research or information.)

References

Turschetal., Tetrahedron, 31,1541 (1975)

Upstream product

• 89959-67-1 (3aα,6aα,9aα)-(+/-)-2-<(n-butylthio)methylene>decahydropyrido<2,1,6-de>quinolizin-1(2H)-one 
• 1214731-32-4 tert-butyl N-[1-(4-pentenyl)-5-hexenyl]carbamate 
• 1214731-28-8 1,13-diethyl (2E,11E)-7-(tert-butoxycarbonylamino)trideca-2,11-dienedioate 
• 97550-44-2 decahydro-1H-pyrido[2,1,6-de]quinolizin-2-one 
• 1214754-51-4 2-methylenedodecahydropyrido[2,1,6-de]quinolizine 
• 1214731-30-2 tert-butyl N-(p-toluenesulfonyl)-N-[1-(4-pentenyl)-5-hexenyl]carbamate 
• 69856-80-0 6-hydroxy-1,10-undecadiene 
• 1130-59-2 dodecahydro-9b-bora-phenalene 
• 138770-30-6 [(2R,4S,6S,9aS)-2-(tert-Butyl-dimethyl-silanyloxy)-6-ethoxycarbonylmethyl-octahydro-quinolizin-4-yl]-acetic acid ethyl ester 
• 138770-30-6 [(2S,6R,9aR)-2-(tert-Butyl-dimethyl-silanyloxy)-6-ethoxycarbonylmethyl-octahydro-quinolizin-4-yl]-acetic acid ethyl ester 
• 138770-27-1 (E)-(S)-6-((2R,6R)-6-Ethoxycarbonylmethyl-piperidin-2-yl)-5-hydroxy-hex-3-enoic acid ethyl ester 
• 138770-28-2 ((2S,6R,9aR)-6-Ethoxycarbonylmethyl-2-hydroxy-octahydro-quinolizin-4-yl)-acetic acid ethyl ester 
• 138770-26-0 (E)-4-((2S,3aR,7R)-7-Ethoxycarbonylmethyl-hexahydro-isoxazolo[2,3-a]pyridin-2-yl)-but-3-enoic acid ethyl ester 
• 138770-32-8 (3aS,5R,6aS,9aS)-5-(tert-Butyl-dimethyl-silanyloxy)-decahydro-pyrido[2,1,6-de]quinolizin-2-one 

Downstream Products

• 34290-97-6 myrrhine N-oxide 

Relevant academic research and scientific papers

Two-directional synthesis as a tool for diversityoriented synthesis: Synthesis of alkaloid scaffolds

Two-directional synthesis represents an ideal strategy for the rapid elaboration of simple starting materials and their subsequent transformation into complex molecular architectures. As such, it is becoming recognised as an enabling technology for divers

Diversity-oriented synthesis of bicyclic and tricyclic alkaloids

A diversity-oriented synthesis involving a cascade sequence, taking linear aminoalkenes to polycyclic scaffolds reminiscent of natural alkaloids, is presented.

An intramolecular aza-[3 + 3] annulation approach to azaphenalene alkaloids. Total synthesis of myrrhine

A detailed account on the stereoselective total syntheses of azaphenalene alkaloids via an intramolecular aza-[3 + 3] annulation strategy is described here. All five members of the Coccinellidae family of defensive alkaloids were prepared from the same co

Combining two-directional synthesis and tandem reactions:? an efficient strategy for the total syntheses of (±)-hippodamine and (±)-epi-hippodamine

Two-directional total stereoselective syntheses of (±)-hippodamine and (±)-epi-hippodamine, utilising a tandem deprotection/intramolecular double Michael addition sequence as the key step, are presented.

Nitrone Cycloaddition-based Entry to the Coccinelline Alkaloid Skeleton: Synthesis of (+/-)-epi-Hippodamine

Synthesis of intermediate 13 possessing the perhydropyridoquinolizine skeleton of the coccinelline alkaloids and conversion to epi-hippodamine 20 was accomplished with stereochemical control arising from a key cycloaddition reaction of nitrone 2 with ethyl hexa-3,5-dienoate.

Stereo- and Regioselective Total Synthesis of the Hydropyridoquinolizine Ladybug Defensive Alkaloids

The stereo- and regioselective syntheses of the ladybug defensive alkaloids coccinelline (1), precoccinelline (2), (+/-)-hippodamine (3), (+/-)-convergine (4), (+/-)-hippocasine (5), (+/-)-hippocasine oxide (6), myrrhine (7), (+/-)-propyleine (8), and (+/-)-isopropyleine (9) are described starting from perhydroboraphenalene.

SYNTHESIS OF THE LADYBUG DEFENSIVE AGENTS (+-)-HIPPODAMINE, (+-)-CONVERGINE, (+-)-HIPPOCASINE AND (+-)-HIPPOCASINE OXIDE

The total syntheses of the ladybug defensive agents (+-)-hippoidamine, (+-)-convergine, (+-)-hippocasine, and (+-)-hippocasine oxide are described starting from perhydroboraphenalene.