58238-45-2

Usage

Uses

Used in Biochemical Research:
.beta.-D-erythro-Hexopyranos-2-ulose, 1,6-anhydro-3-deoxyis used as a research compound for studying metabolic pathways and its role as a precursor to other important compounds. Its cyclic structure formation makes it a valuable subject for understanding various biochemical processes.
Used in Pharmaceutical Research:
.beta.-D-erythro-Hexopyranos-2-ulose, 1,6-anhydro-3-deoxyis used as a potential therapeutic agent in the development of treatments for various diseases. Its unique properties and ability to form cyclic structures make it a promising candidate for pharmaceutical applications.
Used in Chemical Synthesis:
.beta.-D-erythro-Hexopyranos-2-ulose, 1,6-anhydro-3-deoxyis used as a key intermediate in the synthesis of various chemical compounds, particularly those with potential applications in the pharmaceutical and biochemical industries.
Used in Application Industry:
.beta.-D-erythro-Hexopyranos-2-ulose, 1,6-anhydro-3-deoxyis used as [application type] for [application reason]. (Please provide specific application type and reason for this industry)

Upstream product

• 29514-09-8 (1R,2S,4S,5R)-6,8-dioxabicyclo[3.2.1]octane-2,4-diol 
• 37112-31-5 levoglucosenone 

Downstream Products

• 81685-37-2 C₁₈H₁₆O₈ 
• 34371-14-7 2-deoxy-D-ribonolactone 
• 33647-85-7 isolevoglucosenone 
• 29514-09-8 (1R,2S,4S,5R)-6,8-dioxabicyclo[3.2.1]octane-2,4-diol 
• 58394-32-4 1,6-anhydro-2,3-dideoxy-β-threo-hex-2-enopyranose 
• 29514-08-7 (1R,2S,4R,5R)-6,8-dioxabicyclo[3.2.1]octane-2,4-diol 
• 78508-96-0 (5S)-5-(hydroxymethyl)-5H-furan-2-one 
• 39682-49-0 1,6-anhydro-3,4-dideoxy-D-threo-hexopyranoside and 1,6-anhydro-3,4-dideoxy-D-threo-hexopyranoside 

Relevant academic research and scientific papers

Synthesis and fungicidal activity of methylsulfanylmethyl ether derivatives of levoglucosenone

[Figure not available: see fulltext.] A series of derivatives were synthesized on the basis of levoglucosenone that contained hydroxy groups at the С-4 atom or С-2 and С-4 atoms or a hydroxy and methyl group at the С-4 atom. In addition, 4-hydroxymethylbutanolides were synthesized. Derivatives containing hydroxy groups were obtained as methylsulfanylmethyl ethers. It was established that compounds containing a 6,8-dioxabicyclo[3.2.1]-octane ring exhibited fungicidal activity against Rhizoctonia solani. It was shown that the presence of a methylsulfanylmethyl moiety in the ring could increase the fungicidal activity of compounds.

Enzymatic reduction of levoglucosenone by an alkene reductase (OYE 2.6): A sustainable metal- and dihydrogen-free access to the bio-based solvent Cyrene

Levoglucosenone (LGO) has been successfully converted into the green polar aprotic solvent 2H-LGO (aka Cyrene) through an enzymatic process involving alkene reductases: wild-type Old Yellow Enzyme 2.6 (OYE 2.6 wt.) from Pichia stipitis and its mutant (OYE 2.6 Tyr78Trp) present the best conversion rates. This enzymatic process has been optimized in order to avoid the formation of the side-product (1R,2S)-2-hydroxy-6,8-dioxabicyclo[3.2.1]octan-4-one (OH-LGO) and reach total conversion (99%). Cyrene was then successfully isolated by continuous extraction in quantitative yield (99%).

Manipulating the enone moiety of levoglucosenone: 1,3-Transposition reactions including ones leading to isolevoglucosenone

The manipulation of the enone moiety associated with the biomass-derived, homochiral and now abundant compound levoglucosenone (1) is described. While the trichloroacetimidates derived from the allylic alcohols 3 and 4 failed to engage in Overman-type rea

BASE-CATALYZED OLIGOMERIZATION OF LEVOGLUCOSENONE

Heating levoglucosenone in aqueous triethylamine gives a dimer and two trimers in yields of 8, 18, and 56percent, respectively.These compounds have been isolated crystalline, and their structures and stereochemistry have been investigated by (13)C- and (1)H-n.m.r. and other spectroscopic methods.These data indicate that the dimer is apparently formed by Michael addition to provide a C-3-C-4-linked, cyclic trimer and an olefinic, cyclic trimer containing two C-3-C-4 linkages and one C-2-C-3 linkage.