58247-39-5Relevant academic research and scientific papers
Polymethylated and poly(tert)butylated diphenylcarbenes. Generation, reactions, kinetics, and deuterium isotope effects of sterically congested triplet carbenes
Tomioka, Hideo,Okada, Hidetsumu,Watanabe, Tetsuya,Banno, Kohji,Komatsu, Kazunori,Hirai, Katsuyuki
, p. 1582 - 1593 (2007/10/03)
Dimesitylcarbene (2a) was shown to decay by undergoing dimerization and to have a half-life of 160 ms, some 5 orders of magnitude longer-lived than diphenylcarbene. Didurylcarbene (2b) was twice as long-lived as 2a, while decamethyldiphenylcarbene (2c) de
