58253-89-7Relevant academic research and scientific papers
STEREOSELECTIVITY AT BENZYLIC CARBON. FLAVANOIDS-V. SYNTHESIS OF TRANS-4-ACETAMIDOFLAVANS
Hirwe, A.,Marathe, K. G.,Mohorkar, S. S.,Ramdas, K.,Singh, C. B.
, p. 1539 - 1546 (2007/10/02)
Some reactions of 4-substituted flavans have been studied. 4-Chloro/bromo derivatives react under neutral conditions with phthalimide and acetonitrile leading to displacement of axial halogen by nitrogen with inversion.In contrast, irrespective of the ste
Synthesis of 4-Substituted Flavans from 4α-Halogenoflavans
Brown, Ben R.,Guffogg, Stephen,Kahn, Michael L.,Smart, John W.,Stuart, Ian A.
, p. 1825 - 1829 (2007/10/02)
The reactions of flavan-4α- or -4β-ols unsubstituted in ring A with phosphorus or similar halides give 4α-halogenoflavans which react with a variety of nucleophiles (phenolate ions, thiophenolate ions, amines, and alcohols) yielding the corresponding 4-su
