5827-72-5

Upstream product

• 892-20-6 triphenylstannane 
• 107-13-1 acrylonitrile 

Downstream Products

• 6788-69-8 (2-cyano-ethyl)-diphenyl tin ⁽¹⁺⁾; iodide 
• 112714-43-9 Na⁽¹⁺⁾*(C₆H₅)3SnCH₂CH₂COO^(1-)=(C₆H₅)3SnCH₂CH₂COONa 
• 157843-26-0 2-(tributylstannyl)-5-[2-(triphenylstannyl)ethyl]tetrazole 
• 157843-32-8 5-(2-[(diethyldithiocarbamato)diphenylstannyl]ethyl)tetrazole 
• 157843-27-1 2,2-diphenyl-1,6,7,8-tetraaza-2-stannabicyclo[3.3.0]octa-5,7-diene 
• 157843-30-6 5-[2-(chlorodiphenylstannyl)ethyl]tetrazole 
• 157843-33-9 2-bromo-2-phenyl-1,6,7,8-tetraaza-2-stannabicyclo[3.3.0]octa-5,7-diene 
• 157843-36-2 bromo(2-cyanoethyl)diphenylstannane 

Relevant academic research and scientific papers

Organotin chemistry XI. (2-cyanoethyl)tin bromides

The syntheses of bis(2-cyanoethyl)tin dibromide and (cyanoethyl)-tin tribromide by reaction of bromine with diphenylbis(2-cyanoethyl)tin and triphenyl(2-cyanoethyl)tin, respectively, in an inert solvent are reported. Based on the nitrile absorption bands in nujol, it is concluded that tris(2-cyanoethyl)tin bromide and (2-cyanoethyl)tin tibromide, but not bis(2-cyanoethyl)tin dibromide, are associated in the solid state. The nature of these associations are discussed in detail. Molecular weight determinations show that tris(2-cyanoethyl)tin bromide and bis(2-cyanoethyl)tin dibromide are monomeric in tetrahydrofuran and that (2-cyanoethyl)tin tribromide is monomeric in benzene.

Polarity-reversal-catalyzed hydrostannylation reactions: Benzeneselenol-mediated homolytic hydrostannylation of electron-rich olefins

Addition of 10 mol-% of diphenyl diselenide to hydrostannylation reactions involving electron-rich olefins results in a dramatic improvement in yield. For example, reaction of α-([(tert-butyl)dimethylsilyl]-oxy}styrene (1) with triphenylstannane (2a; 1.1